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Are the Local Electrophilicity Descriptors Reliable Indicators of Global Electrophilicity Trends?
The Journal of Physical Chemistry A, 2005Density functional theory based global and local electrophilicity descriptors are used to study the reliability of local electrophilicity values of the strongest electrophilic sites in generating global intermolecular electrophilicity trends.
Ram Kinkar, Roy +3 more
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Reactions of aminomalononitrile with electrophiles
Journal of Molecular Evolution, 1975Aminomalononitrile (HCN trimer) reacts with electrophiles such as aldehydes and acrylonitrile under very mild conditions of temperature and pH to produce intermediates which, after acid hydrolysis, yield amino acids. The following amino acids have been identified and quantitated: glycine, D, L-erythro- and D, L-threo-beta - hydroxyaspartic acids, D, L ...
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Electrophilic eicosanoids: Signaling and targets
Chemico-Biological Interactions, 2011Electrophilic eicosanoids are reactive mediators that arise by non-enzymatic transformations of arachidonic acid or of its products and display varied biological actions. Various electrophilic eicosanoids have shown anti-proliferative and anti-inflammatory effects, which have elicited a great interest in their study as potential therapeutic agents.
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Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Phosphates With Aryl Bromides
Advanced Synthesis and Catalysis, 2023Mengtao Ma +2 more
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Iron-Catalyzed Cross-Electrophile Coupling of Inert C–O Bonds With Alkyl Bromides
CCS Chemistry, 2023Zhang Feng, Qian Peng, Yun He
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