Molecular & Cellular Proteomics, 2013 We present the first comprehensive capillary electrophoresis electrospray ionization mass spectrometry (CESI-MS) analysis of post-translational modifications derived from H1 and core histones.
B. Sarg +5 more
semanticscholar +1 more source
Variational autoencoders for tissue heterogeneity exploration from (almost) no preprocessed mass spectrometry imaging data [PDF]
arXiv, 2017 The paper presents the application of Variational Autoencoders (VAE) for data dimensionality reduction and explorative analysis of mass spectrometry imaging data (MSI). The results confirm that VAEs are capable of detecting the patterns associated with the different tissue sub-types with performance than standard approaches.
arxiv
The path of biomolecular mass spectrometry into open research
Nature Communications, 2019 Originally designed for measuring isotope abundances and elemental masses, mass spectrometry is becoming a mainstay across life sciences. As electrospray ionization of biomolecules turns 30 and the Orbitrap mass analyzer 20, we take this opportunity to ...
doaj +1 more source
Radical Mechanism in the Elimination of 2-Arylsulfinyl Esters [PDF]
, 2012 The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work.
González, Florenci +6 more
core +1 more source
Molecules, 2013 The present study investigates the chemical composition of the African plant Parkia biglobosa (Fabaceae) roots and barks by Liquid Chromatography - Electrospray Ionization and Direct Injection Tandem Mass Spectrometry analysis.
Wagner Vilegas +5 more
doaj +1 more source
Rapid and comprehensive evaluation of (poly)phenolic compounds in pomegranate (punica granatum L.) juice by UHPLC-MSn [PDF]
, 2012 The comprehensive identification of phenolic compounds in food and beverages is a crucial starting point for assessing their biological, nutritional, and technological properties.
Alan Crozier +21 more
core +2 more sources
Top-Down Mass Spectrometry Imaging of Intact Proteins by LAESI FT-ICR MS [PDF]
arXiv, 2013 Laser Ablation Electrospray Ionization is a recent development in mass spectrometry imaging. It has been shown that lipids and small metabolites can be imaged in various samples such as plant material, tissue sections or bacterial colonies without anysample pre-treatment.
arxiv
Charge emissions from Electrosprays in vacuum: mixtures of formamide with methylammonium formate [PDF]
D. Garoz y J. Fernandez de la Mora, Journal of Applied Physics,
vol. 113, n. 6, pp. 064901-064901-8, feb. 2013The charge/mass distribution f(q/m) of nanodrops and ions electrosprayed in vacuum from mixtures of formamide (FM) and methylammonium formate (MAF) is studied by time of flight mass spectrometry at MAF/FM volumetric concentrations of 5%, 10%, 25% and 50%.
arxiv +1 more source
An Organic Chemist’s Guide to Electrospray Mass Spectrometric Structure Elucidation
Molecules, 2019 Tandem mass spectrometry is an important tool for structure elucidation of natural and synthetic organic products. Fragmentation of odd electron ions (OE+) generated by electron ionization (EI) was extensively studied in the last few decades, however ...
Arnold Steckel, Gitta Schlosser
doaj +1 more source
Recent advances in experimental techniques to probe fast excited-state dynamics in biological molecules in the gas phase : dynamics in nucleotides, amino acids and beyond [PDF]
, 2013 In many chemical reactions, an activation barrier must be overcome before a chemical transformation can occur. As such, understanding the behaviour of molecules in energetically excited states is critical to understanding the chemical changes that these ...
Hadden DJ +6 more
core +1 more source