Results 81 to 90 of about 203,215 (351)

A Dual‐Emissive DNA‐Templated Silver Nanocluster with Near‐Infrared I and II Emission

open access: yesAdvanced Optical Materials, Volume 13, Issue 8, March 13, 2025.
This study presents a dual‐emissive DNA‐stabilized silver nanocluster with a nanosecond‐lived NIR‐I emission band and a microsecond‐lived NIR‐II emission band. Mass spectrometry establishes that the nanocluster has molecular formula (DNA)2[Ag17]11+. DNA sequence variations reveal critical nucleobases for stabilization, and modifications at the DNA 5 ...
Anna Gonzàlez‐Rosell   +6 more
wiley   +1 more source

Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
In the presence of a Pd0 catalyst, large π‐extended arynes trimerize in an unusual manner to forge extremely compact and strained chiral benzenoids. This new trimerization reaction involves a 1,7‐Pd isomerization, a rare and poorly understood process that is elucidated.
Albert Artigas   +6 more
wiley   +1 more source

A targeted mass spectrometric analysis of phosphatidylinositol phosphate species

open access: yesJournal of Lipid Research, 2005
The development of a new mass spectrometric lipid profiling methodology permits the identification of cellular phosphatidylinositol monophosphate/phosphatidylinositol bisphosphate/phosphatidylinositol trisphosphate (PIP/PIP2/PIP3) species that includes ...
Stephen B. Milne   +4 more
doaj  

Naphthalimide Derivatives as Film‐Based Fluorescent Sensors for Rapid Detection of Illicit Drugs

open access: yesAdvanced Sensor Research, EarlyView.
Four novel 1,8‐naphthalimide (NI) derivatives for the detection of illicit drugs with different substituents at the 4‐position are reported. Their contrasting fluorescence responses enables five illicit drugs to be distinguished from interferents with a mean classification accuracy of 81%.
Ming Chen   +7 more
wiley   +1 more source

Espectrometria de massas com ionização por "electrospray": processos químicos envolvidos na formação de íons de substâncias orgânicas de baixo peso molecular

open access: yesQuímica Nova, 2006
An overview of the current literature on the chemical processes involved in the ion formation from low molecular weight organic compounds by electrospray ionization mass spectrometry is given.
Crotti Antônio Eduardo Miller   +3 more
doaj  

Polyoxometalate Imide‐Linked Molecules, Covalent Organic Polymers, and Frameworks: Dimensionality Effects on Supercapacitors Performance

open access: yesAdvanced Sustainable Systems, EarlyView.
This study explores polyoxometalate‐based hybrids with varying dimensionalities, linking molecular, polymeric, and framework structures to supercapacitor performance. The results highlight how structural tuning enhances surface area, porosity, and charge transport, offering insights into designing efficient energy storage materials.
Daria Nowicka   +6 more
wiley   +1 more source

Nicotine Reprograms Aging‐Related Metabolism and Protects Against Motor Decline in Mice

open access: yesAdvanced Science, EarlyView.
Long‐term oral nicotine intake protects against age‐related motor decline in mice without eliciting systemic toxicity. Integrated multi‐organ metabolomic profiling and longitudinal gut microbiota analyses reveal that nicotine induces coordinated remodeling of glycolipid and sphingolipid metabolism, enhances NAD⁺ bioavailability, and suppresses ceramide
Shuhui Jia   +29 more
wiley   +1 more source

Tissue imaging using nanospray desorption electrospray ionization mass spectrometry.

open access: yesAnalytical Chemistry, 2012
Ambient ionization imaging mass spectrometry is uniquely suited for detailed spatially resolved chemical characterization of biological samples in their native environment.
J. Laskin   +4 more
semanticscholar   +1 more source

Mesenchymal Stromal Cell Secretome and Its Key Bioactive Metabolites Induce Long‐Term Neuroprotection After Traumatic Brain Injury in Mice

open access: yesAdvanced Science, EarlyView.
Pischiutta F and coworkers identify prostaglandins and kynurenine as key mediators of the mesenchymal stromal cells‐derived secretome's neuroprotective effects. A synthetic cocktail composed of these factors promotes long‐term functional recovery, reduces brain structural damage, and modulates neuroinflammation after traumatic brain injury, supporting ...
Francesca Pischiutta   +24 more
wiley   +1 more source

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