Results 61 to 70 of about 75,325 (204)

Metal‐Ion Regulated Light‐Free Z→E Isomerization of Azobenzene Glycomacrocycle

open access: yesChemistry – A European Journal, EarlyView.
Metal ion‐catalyzed Z→E isomerization of photoswitchable azobenzene glycomacrocycle: A new azobenzene‐based glycomacrocycle is capable of forming a 1:1 complex with divalent metal ions in both E‐ and Z‐isomers. The complexes undergo light‐free Z→E isomerization in a timescale spanning from seconds to weeks.
Yang Zhou   +4 more
wiley   +1 more source

Liquid chromatographic enantiomer separations applying chiral ion-exchangers based on Cinchona alkaloids

open access: yes, 2018
As the understanding of the various biological actions of compounds with different stereochemistry has grown, the necessity to develop methods for the analytical qualification and quantification of chiral products has become particularly important.
Lindner Wolfgang   +3 more
core   +1 more source

Decoding Heptazine Architectures: From Molecular Association to Structural Insight

open access: yesChemistry – A European Journal, EarlyView.
A comprehensive study (NMR and theoretical) of three novel heptazine derivatives that self‐assemble into dimers has been conducted, highlighting their versatility as a platform for multifunctional supramolecular and optoelectronic materials. ABSTRACT Heptazine (Hpz) derivatives display remarkable supramolecular organization governed by noncovalent ...
Silvia del Moral   +5 more
wiley   +1 more source

Determination of Enantiomer in Tofacitinib Citrate Using Reversed-Phase Chiral High-Performance Liquid Chromatography

open access: yes
Tofacitinib citrate (RR-isomer) is a janus kinase (JAK) inhibitor approved for the treatment of rheumatoid arthritis (RA) in adults who have had an inadequate response or intolerance to methotrexate. The presence of the enantiomer of tofacitinib citrate (
Tingting Zhang   +5 more
core   +1 more source

Vibrational Circular Dichroism Spectra of 2,5‐Diaminoterephtalate Macrocycles Reveal Distant Vibrational Exciton Coupling

open access: yesChemistry – A European Journal, EarlyView.
The energy level diagrams for the ν(C═O) and the δ(N─H) vibrations, resulting of combining in‐phase and out‐of‐phase modes on the basis of their local symmetries, was built by applying the exciton coupling theory to a new class of chiral macrocycles, based on the 2,5‐diaminoterephthalate scaffold.
Samara Medina   +4 more
wiley   +1 more source

Bragg crystal monochromators

open access: yesMajor Reference Works, Page 290-301., 2021
International Tables for Crystallography is the definitive resource and reference work for crystallography and structural science.

Each of the eight volumes in the series contains articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the ...
John P. Sutter C. Chantler   +2 more
wiley  

+1 more source

Chiral‐at‐Metal Racemization of Tris‐Chelated Octahedral Complexes: A DFT Case Study of Al(acnac)3

open access: yesChemistry – A European Journal, EarlyView.
Racemization and isomerization of M(a‐chel)3 complexes was unraveled using Al(acnac)3 as a model. The ∆/Λ‐fac isomers have four racemization paths of which one includes isomerization to and racemization of the mer isomer. N‐substitution should enable separation of the ∆‐fac and Λ‐fac enantiomers.
George Dhimba   +2 more
wiley   +1 more source

Enantiomer-Specific Study of Fenpropathrin in Soil-Earthworm Microcosms: Enantioselective Bioactivity, Bioaccumulation, and Toxicity

open access: yes
In this study, the enantiomer-specific bioactivity, bioaccumulation, and toxicity of fenpropathrin (FEN) enantiomers were investigated in soil-earthworm microcosms.
Zan Zhang (161377)   +9 more
core   +1 more source

Prediction of dynamic pairwise wake vortex separations for approach and landing [PDF]

open access: yes, 2012
Design and performance of the Wake Vortex Prediction and Monitoring System WSVBS are described. The WSVBS has been developed to tactically increase airport capacity for approach and landing on single runways as well as closely-spaced parallel runways. It
Schwarz, Carsten   +3 more
core  

Light, Redox, and Ligand Noninnocence Cooperate in Naphthalene Diimide‐Functionalized N‐Heterocyclic Carbene Iridium Complexes

open access: yesChemistry – A European Journal, EarlyView.
Naphthalene diimide–N‐heterocyclic carbene iridium complexes display uncommon multistimuli‐responsive behavior combining strong Cl(lp)···π interactions, ligand non‐innocence, visible‐light photoreduction, and conPET photocatalysis. The study also provides new insight into the interaction of NDI platforms with fluoride/basic anions, revealing unexpected
Maite Silva‐Muñoz   +2 more
wiley   +1 more source

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