Results 161 to 170 of about 667,303 (272)
A molecular motor with four‐state dynamic chirality is integrated into liquid crystals, enabling quadruple sequential helix inversions and high helical twisting power. Due to high motor efficiency, the supramolecular helicity can be controlled by near‐infrared light via upconversion nanoparticles, resulting in a robust, multistate, photoresponsive soft
Jinyu Sheng +3 more
wiley +1 more source
Amino acids in comets and meteorites: stability under gamma radiation and preservation of the enantiomeric excess [PDF]
Susana Iglesias‐Groth +3 more
openalex +1 more source
A stereoselective one‐step (3 + 3)‐cycloaddition between in situ generated pyrrole‐3‐methides and carbonyl ylides has been developed using cooperative rhodium and chiral phosphoric acid catalysis. The reaction affords oxa‐bridged cyclohepta[1,2‐b]pyrroles bearing three stereogenic centers, including two quaternary ones, in high yields and ...
Philipp Stehr, Christoph Schneider
wiley +1 more source
Development of a Copper‐Free Click Reaction for Asymmetric Rh Diene Catalysis Under Confinement
A copper‐free amino–yne click reaction enables the selective functionalization of chiral diene ligands with both soluble and immobilized amines. Substituent‐controlled stereoselectivity affords (E)‐ and (Z)‐enaminone ligands, which are converted into Rh complexes for asymmetric catalysis under homogeneous and heterogeneous conditions.
Manuel Kirchhof +10 more
wiley +1 more source
Persistent Reverse Enantiomeric Excess in Solution during Viedma Ripening
L. Spix +4 more
semanticscholar +1 more source
The advent of aptamers has highlighted their potential as alternatives to antibodies, overcoming limitations of structural instability and production cost. However, conventional approaches such as SELEX remain slow and labor‐intensive. This review examines recent advances in aptamer engineering, emphasizing in vitro and AI‐driven in silico strategies ...
John V. L. Nguyen +5 more
wiley +1 more source
New Method for Synthesizing the Intermediates to 5-HETE from Yeast-mediated Reduction Products by Employing Baeyer-Villiger Oxidation with Complete Retention of Enantiomeric Excess [PDF]
Satoshi Yamauchi +2 more
openalex +1 more source
This work reviews recent advances in Organic Semiconducting Single Crystals (OSSCs), focusing on mechanical flexibility for robust devices, polymorph control for precise phase selection, and interface engineering with self‐assembled monolayers to improve alignment and performance.
Alessando Fraleoni‐Morgera +3 more
wiley +1 more source

