Results 181 to 190 of about 48,679 (293)

Solvent Effects on the Conformational Preferences of 2,6‐Pyridylcarboxamide Foldamers

Chemistry – A European Journal, EarlyView.
The marked effect of organic solvents and water/methanol mixtures on the conformational preferences of a soluble chiral foldamer has been established in a diverse array of seventeen distinct environments. ABSTRACT The marked influence of organic solvents and water on the conformational preferences of a chiral, soluble 2,6‐pyridylcarboxamide foldamer ...
Alexander R. Davis, Sena Öztürk, Kushal Samanta, Louise Male, Adam A. L. Michalchuk, Sarah J. Pike   +5 more
wiley   +1 more source

Decoding chirality at the nanoscale with momentum-space polarimetry. [PDF]

Light Sci Appl
Nayak JK, Sarkar M, Zavatski S, Buhara E, Boroviks S, Martin OJF.   +5 more
europepmc   +1 more source

Structure Elucidation and Total Synthesis of Granolides A–C: Ethyl‐branched Sesquiterpenes From the Tropical Frog Gephyromantis granulatus

Chemistry – A European Journal, EarlyView.
Males of the tropical frog Gephyromantis granulatus carry unique ethyl‐branched sesquiterpenoid macrolactones in their scent glands. Their structure elucidation was performed by GC/MS, leading to the proposed structures of the granolides. A flexible enantioselective synthesis confirmed the structures and allowed determination of their absolute ...
Johanna Kuhn, Miguel Vences, Stefan Schulz   +2 more
wiley   +1 more source

Flipping the Card With Enantiodivergent Organocatalysis

Chemistry – A European Journal, EarlyView.
This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre, Alessio Carioscia, Alessandro Brusa, Armando Carlone   +3 more
wiley   +1 more source

An Amino-Acid-Derived Metal-Organic Framework with Large Pores for Unspecific Enantioseparation. [PDF]

J Am Chem Soc
Ma X, Wang M, Li W, Qi J, Tu S, Zhang L, Wang KY, Fu Y, Han Z, Wu X, Zhou HC, Zhu C.   +11 more
europepmc   +1 more source

Covalent Insertion of a Mn(Salen) Type Complex in Cross‐Linked Protein Crystals: Design of an Enantioselective Artificial Epoxidase

Chemistry – A European Journal, EarlyView.
An Artificial metalloenzyme was designed by a Michael addition between a MnSalen complex and a cysteine residue within NikA crystals. The heterogeneous catalyst was found capable of an enantioselective and stereospecific epoxidation of cis‐β‐methylstyrene in cristallo.
Manel Boukhallat, Ismail Benhamed, Jade Arnone, Stann Van Baaren, Clara Rinaldi, Patrice Catty, Caroline Marchi‐Delapierre, Christine Cavazza, Stéphane Ménage   +8 more
wiley   +1 more source

Enantioselective effects of imazalil on banana postharvest ripening aroma revealed by integrated volatilomics, lipidomics and metabolomics. [PDF]

Food Chem X
Chen X, Zhang Y, Wu Q, Zhuang L, Yang Z, Zhang Q, Tan L, Lan W, Wang M, Ma C, Xu Z, Lyu D.   +11 more
europepmc   +1 more source

Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence

Chemistry – A European Journal, EarlyView.
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen, Zong‐Ying Liu, Jhon Sebastian Oviedo Ortiz, Nicolas Vanthuyne, Jeanne Crassous, Ondřej Mrózek, Fabien B. L. Cougnon, Wen‐Yi Hung, Pi‐Tai Chou, Igor O. Koshevoy, Andrey Belyaev   +10 more
wiley   +1 more source

Exploring the potential of β-Cyclodextrin@Ti₃C₂T_x MXene in electrochemical chiral recognition of tyrosine enantiomers. [PDF]

Mikrochim Acta
Hasanova S, Gumus E, Akbayrak S, Zor E.
europepmc   +1 more source

Post‐Modification of Tripyrenylenes to Enantiopure π‐Extended D3‐Symmetric Propellers

Chemistry – A European Journal, EarlyView.
The post‐modification of tripyrenylenes to π‐extended enantiopure propellers with tris‐phenanthrophenazines is presented and the chiroptical properties as well as the solid‐state packings investigated in comparison to the corresponding racemic mixtures.
Dennis Popp, Melanie Bruttel, Sebastian Möbert, Anusha Sounder Rajan, Christoph Keck, Darius Boehm, Frank Rominger, Sven M. Elbert, Michael Mastalerz   +8 more
wiley   +1 more source