Increased sensitivity in electron–nuclear double resonance spectroscopy with chirped radiofrequency pulses [PDF]
Magnetic ResonanceElectron–nuclear double resonance (ENDOR) spectroscopy is an EPR technique to detect the nuclear frequency spectra of hyperfine coupled nuclei close to paramagnetic centers, which have interactions that are not resolved in continuous wave EPR spectra and
J. Stropp +3 more
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EPR spectroscopy reveals antioxidant manganese defenses in the Lyme disease pathogen Borrelia burgdorferi [PDF]
mBioOxidative stress defense in aerobic bacteria relies on Mn-superoxide dismutase (MnSOD) and antioxidant Mn-metabolite complexes (H-Mn) to quench superoxide radicals (O2•−).
Andrés F. Londoño +9 more
doaj +2 more sources
Bidentate Substrate Binding Mode in Oxalate Decarboxylase [PDF]
MoleculesOxalate decarboxylase is an Mn- and O2-dependent enzyme in the bicupin superfamily that catalyzes the redox-neutral disproportionation of the oxalate monoanion to form carbon dioxide and formate.
Alvaro Montoya +3 more
doaj +2 more sources
Laser Pulses for Studying Photoactive Spin Centers with EPR [PDF]
MicromachinesQuantum technologies are currently being explored for various applications, including computing, secure communication, and sensor technology. A critical aspect of achieving high-fidelity spin manipulations in quantum devices is the controlled optical ...
George Mamin +5 more
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Flavoproteins as native and genetically encoded spin probes for in cell ESR spectroscopy [PDF]
Nature CommunicationsFlavin cofactors are attractive Electron Spin Resonance (ESR) probes for proteins because cellular reductants and light can generate their semiquinone states.
Timothée Chauviré +4 more
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Aerodynamic Optimization Design of a Supersonic Compressor Rotor with High Pressure Ratio
International Journal of Aerospace Engineering, 2021 Supersonic compressors have a high wheel speed and operational capability, which facilitate a high stage pressure ratio. However, the strong shock waves in the passage of a supersonic rotor and the interference between shock waves and boundary layers can
Cui Cui, Zhenggui Zhou, Endor Liu
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ENDOR of Organic Radicals in Solution
CHIMIA, 1972 A survey is given over the end or method as applied to organic doublet radicals in solution. After discussing the experimental requirements for successful end or-in-solution work, selected examples are presented which demonstrate the power and ...
Klaus Möbius, Klaus-Peter Dinse
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A primer in pulse EPR-based hyperfine spectroscopy for NMR spectroscopists
Journal of Magnetic Resonance Open, 2023 The theoretical foundations of NMR and EPR are very similar. Nevertheless, the fields differ significantly in practical aspects. This primer is an attempt to bridge some of the gaps between the fields, and at the same time it highlights some applications
Nino Wili
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Cross-polarisation edited ENDOR [PDF]
Molecular Physics, 2013 Electron-nuclear double resonance (ENDOR) is a fundamental technique in electron paramagnetic resonance (EPR) spectroscopy that directly detects hyperfine transitions of nuclei coupled to a paramagnetic centre. Despite its wide use, spin-sensitivity and restricted spectral resolution in powder samples pose limitations of this technique in modern ...
Rizzato, R. +3 more
openaire +3 more sources
Electron nuclear double resonance study of photostimulated luminescence active centers in CsBr:Eu2+ medical imaging plates [PDF]
, 2011 CsBr:Eu2+ needle image plates exhibit an electron-paramagnetic-resonance (EPR) spectrum at room temperature (RT), whose intensity is correlated with the photostimulated luminescence sensitivity of the plate.
Callens, Freddy +5 more
core +2 more sources