The diastereoselective Meth-Cohn epoxidation of camphor-derived vinyl sulfones [PDF]
Some camphor-derived vinyl sulfones bearing oxygen functionality at the allylic position have been synthesized and their nucleophilic epoxidation reactions under Meth-Cohn conditions have been explored.
Adam+91 more
core +1 more source
A Practical Guide to Heterogeneous Catalysis in Hydrocarbon Transformations
A focused overview of the catalytic processing of hydrocarbons to transform them into more valuable compounds is presented. This work is intended to assist BSc, MSc, and PhD students, as well as junior researchers, in selecting and performing appropriate heterogeneous catalytic processes for specific heterogeneous catalytic reactions.
Kelvin A. Sanoja‐Lopez+5 more
wiley +1 more source
Lubrication properties of sunflower oil have been modified by epoxidation in the first step and acetylation of the obtained epoxide in the second step.
J. Ashrafi+3 more
doaj +1 more source
Investigation of macrocyclisation routes to 1,4,7-triazacyclononanes : efficient syntheses from 1,2-ditosylamides [PDF]
Two routes to the synthesis of a cyclohexyl-fused 1,4,7-triazacyclononane involving macrocyclisations of tosamides have been investigated. In the first approach, using a classic Richman-Atkins-type cyclisation of a cyclohexyl-substituted 1,4,7 ...
Gibson, C.L.+6 more
core +1 more source
Reversible Restructuring of Silver Particles during Ethylene Epoxidation
The restructuring of a silver catalyst during ethylene epoxidation under industrially relevant conditions was investigated without and with vinyl chloride (VC) promotion.
A. V. van Hoof+3 more
semanticscholar +1 more source
Poly(ethylene Glycol)‐Based Peptidomimetics (Pegtides) of Antimicrobial Peptides
Polyethylene glycol (PEG) is commonly used to improve the pharmacokinetics and pharmacodynamics of therapeutic candidates by conjugation. Here PEG is exploited for peptidomimetic conversion of antimicrobial peptides (AMPs), as candidate antibacterial agents, by replacing their polyamide backbone. The pegtides obtained thereby can be readily synthesized
Conor Shine+13 more
wiley +1 more source
Safranal epoxide – A potential source for diverse therapeutic applications
Safranal is an organic compound isolated from saffron oil. Photo epoxidation and thermal reactions of safranal can be a significant tool for the design of drugs to act as anticancer agents and potent chemoprevention.
Suzan Khayyat, Eman Elgendy
doaj +1 more source
Knock-Out of the Genes Coding for the Rieske Protein and the ATP-Synthase δ-Subunit of Arabidopsis [PDF]
In Arabidopsis, the nuclear genes PetC and AtpD code for the Rieske protein of the cytochrome b6/f (cyt b6/f) complex and the δ-subunit of the chloroplast ATP synthase (cpATPase), respectively.
Dietzmann, Angela+8 more
core +1 more source
Indole Synthesis via Allenyl Ester; Enantioselective Total Synthesis of Geissoschizoline
An indole synthesis via an allenyl ester intermediate at ambient temperature has been developed. The mild reaction conditions allow the use of a broad range of substrates. Notably, the utility of this approach is demonstrated through the asymmetric total synthesis of geissoschizoline, a Strychnos‐type monoterpenoid indole alkaloid.
Sohsuke Moriue+5 more
wiley +1 more source
Total syntheses of conformationally-locked difluorinated pentopyranose analogues and a pentopyranosyl phosphate mimetic [PDF]
Trifluoroethanol has been elaborated, via a telescoped sequence involving a metalated difluoroenol, a difluoroallylic alcohol, [2,3]-Wittig rearrangement, and ultimately an RCM reaction and requiring minimal intermediate purification, to a number of ...
Miles, Jonathan A. L.+4 more
core +1 more source