Results 101 to 110 of about 84,237 (324)
The moss Bryum argenteum var. muticum Brid. is well adapted to cope with high light in continental Antarctica [PDF]
The net photosynthetic rate (NP), chlorophyll fluorescence, carotenoid content and chlorophyll content of the cosmopolitan moss Bryum argenteum were measured in the field at Botany Bay, southern Victoria Land, continental Antarctica (77°S).
Green, T.G. Allan +5 more
core +3 more sources
Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger +3 more
wiley +1 more source
ROLE OF Mn(TPP)Cl IN THE EPOXIDATION WITH SINGLET OXYGEN [PDF]
Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is ...
doaj
Selective and metal-free epoxidation of terminal alkenes by heterogeneous polydioxirane in mild conditions [PDF]
Polydioxirane (PDOX) was prepared by the treatment of polysalicylaldehyde with Oxone and was found as a selective, highly efficient and heterogeneous reagent for epoxidation of alkenes which can be successfully isolated.
M. Kazemnejadi +4 more
doaj +1 more source
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
wiley +1 more source
Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies
A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley +1 more source
Lipase-mediated epoxidation of alkenes in supercritical carbon dioxide
In this work, supercritical carbon dioxide was used as reaction media in the lipase-mediated epoxidation of alkenes for the first time. Under the optimal conditions (alkene (1 mmol), novozym 435 (15 mg), H2O2 (50% aqueous solution, 1.4 mmol), n-caprylic ...
Jiaxin Zhang +7 more
doaj +1 more source
Multiple OCP isomers and/or metabolites along with their parent compounds were detected in commonly consumed fruits and vegetables of Bangladesh, possibly attributed to both recently and historically applied OCPs. However, all the detected values were below 0.01 mg/kg, indicating no potential human health risks through dietary intake. ABSTRACT Globally,
Kazi Sanjana Adnen +4 more
wiley +1 more source
Chemoenzymatic Epoxidation of Alkenes and Reusability Study of the Phenylacetic Acid
Here, we focused on a simple enzymatic epoxidation of alkenes using lipase and phenylacetic acid. The immobilised Candida antarctica lipase B, Novozym 435 was used to catalyse the formation of peroxy acid instantly from hydrogen peroxide (H2O2) and ...
Emilia Abdulmalek +5 more
doaj +1 more source
Epoxidation of the C=C double bond in unsaturated norlignans derived from hydroxymatairesinol was studied. The intermediate epoxides were formed in up to quantitative conversions and were readily further transformed into tetrahydrofuran, aryltetralin ...
Patrik A. Runeberg +2 more
doaj +1 more source

