Results 61 to 70 of about 59,417 (298)

Enhancing the Mechanical Properties of Inherently Brittle, Biobased and Biodegradable Polyhydroxybutyrate (PHB) Polymer by Cotton Fibre Reinforcement and Interfacial Grafting

open access: yesAdvanced Sustainable Systems, EarlyView.
This study enhances biobassed, biodegradable polyhydroxybutyrate (PHB)s strength and ductility by reinforcing it with polyvinyl alcohol (PVA)‐coated cotton fibres and further improving interfacial bonding through maleic anhydride (MA) grafting. In addition to mechanical performance, the approaches significantly improve the gas barrier properties of the
Yilin He   +6 more
wiley   +1 more source

Surface decorated magnetite nanoparticles with birhodanine and MoO2Cl2(dmf)2 as a new magnetic catalyst for epoxidation of olefins [PDF]

open access: yesJournal of Particle Science and Technology, 2019
In this work, the synthesis and characterization of a new magnetically supported Mo6+ complex have been reported as a catalyst for epoxidation of olefins. For this purpose, a new silylating compound containing a birhodanine moiety, i.e.
Arman Rahmaninia   +4 more
doaj   +1 more source

Engineering Electron Transfer Flux between Cytochrome P450 Enzyme and P450 Reductase to Enhance Serotonin Production in Escherichia Coli

open access: yesAdvanced Science, EarlyView.
The electron transfer flux in CPR‐P450 catalytic system is systematically engineered through: i) enhancing electron transfer rate by redesigning the putative electron transfer pathway of CPR; ii) improving electron‐receiving rate by evolving the heme domain of tryptophan‐5‐hydroxylase (T5H); iii) enlarging electron supply by fine‐tuning NADPH synthesis.
Wenzhao Xu   +4 more
wiley   +1 more source

Nanocluster polyoxomolybdate, (NH4)12[Mo36(NO)4O108(H2O)16] as an efficient catalyst in olefins epoxidation [PDF]

open access: yesشیمی کاربردی روز, 2016
In this project, epoxidation of olefins using nanocluster polyoxomolybdate, (NH4)12[Mo36(NO)4O108(H2O)16] in presence of  tert- butyl hydroperoxide (TBHP) were studied.
مجتبی امینی
doaj   +1 more source

Synthesis of Crosslinked Biopolyesters Catalyzed by Natural Amino Acids

open access: yesAsian Journal of Organic Chemistry, EarlyView.
Highly crosslinked bio‐polyesters were synthesized via the ROCOP reaction between epoxidized sunflower oil and biobased cyclic anhydrides. The resulting materials were comprehensively characterized by FT‐IR, TGA, and DSC. A cross‐linked network in the bio‐based polymers has been confirmed by dynamic mechanical analysis.
Enrique Francés‐Poveda   +9 more
wiley   +1 more source

Asymmetric Epoxidation: A Twinned Laboratory and Molecular Modeling Experiment for Upper-Level Organic Chemistry Students [PDF]

open access: yes, 2015
The coupling of a student experiment involving the preparation and use of a catalyst for the asymmetric epoxidation of an alkene with computational simulations of various properties of the resulting epoxide is set out in the form of a software toolbox ...
Hii, KKM, Rzepa, HS, Smith, EH
core   +3 more sources

The quantum chemical study of the mechanism of the epoxidation reaction of limonene and geraniol with peracetic and perbenzoic acids

open access: yesЖурнал органічної та фармацевтичної хімії, 2019
Aim. To compare the mechanism of the epoxidation reaction of terpenes Geraniol and Limonene with peracetic acid and perbenzoic acid based on the quantum chemical study. Materials and methods.
O. M. Agafonov   +2 more
doaj   +1 more source

Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications [PDF]

open access: yes, 2017
Layered double hydroxides (LDHs) are an important large class of two-dimensional (2D) anionic lamellar materials that possess flexible modular structure, facile exchangeability of inter-lamellar guest anions and uniform distribution of metal cations in ...
Li, Tengfei   +2 more
core   +1 more source

The Chemistry and Biology of the Tetrodotoxin Natural Product Family

open access: yesAngewandte Chemie International Edition, Accepted Article.
Tetrodotoxin is a neurotoxic marine alkaloid, first isolated in 1909 from pufferfish and named after the biological order tetraodontiformes. Since its structural elucidation in 1964, it has attracted the interest of synthetic organic chemists due to its exceptional polarity, complex architecture, and important biological activity.
Benedikt Nißl   +6 more
wiley   +1 more source

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