Divinylglycol, a Glycerol-Based Monomer: Valorization, Properties, and Applications [PDF]
Green Polymer Chemistry: New Products, Processes, and
Applications, pp.299-330, 2018, 2019 In the context of the development of bio-refineries, glycerol and its derivatives are co-products of the oleochemistry for which new valorization routes must be found. In this study, the polymerizability of divinylglycol (DVG), a symmetrical C-6 glycerol derivative which bears a vicinal diol and two vinyl functions was studied.
arxiv +1 more source
Surface decorated magnetite nanoparticles with birhodanine and MoO2Cl2(dmf)2 as a new magnetic catalyst for epoxidation of olefins [PDF]
Journal of Particle Science and Technology, 2019 In this work, the synthesis and characterization of a new magnetically supported Mo6+ complex have been reported as a catalyst for epoxidation of olefins. For this purpose, a new silylating compound containing a birhodanine moiety, i.e.
Arman Rahmaninia +4 more
doaj +1 more source
A Computational Investigation of the Catalytic Properties of Graphene Oxide: Exploring Mechanisms Using DFT Methods [PDF]
ChemCatChem 4, 1844-184 (2012), 2012 Here we describe a computational study undertaken in an effort to elucidate the reaction mechanisms behind the experimentally observed oxidations and hydrations catalyzed by graphene oxide (GO). Using the oxidation of benzyl alcohol to benzaldehyde as a model reaction, density functional theory (DFT) calculations revealed that this reactivity stemmed ...
arxiv +1 more source
Lactose as an inexpensive starting material for the preparation of aldohexos-5-uloses: synthesis of L-ribo and D-lyxo derivatives [PDF]
, 2010 SUMMARY: Partially protected derivatives of L-ribo- and D-lyxo-aldohexos-5-ulose have been prepared starting from triacetonlactose dimethyl acetal derivatives.
Catelani, Giorgio +2 more
core +1 more source
Journal of Catalysis, 2018 Chemical looping epoxidation of ethylene was demonstrated, whereby the sole oxidant was a solid oxygen carrier, 15 wt% Ag supported on SrFeO3. Ethylene reacted with a bed of carrier particles, without any O2(g) in the feed, to produce ethylene oxide (EO) and CO2.
Chan, MSC +3 more
openaire +2 more sources
Arabian Journal of Chemistry, 2023 This article describes the preparation of chloroacetated natural rubber (CNR) through the epoxidation of natural rubber (NR) latex with performic acid, followed by the reaction with chloroacetic acid.
Terana Senakham +5 more
doaj
Heterogenisation of ketone catalysts within mesoporous supports for asymmetric epoxidation
, 2013 The synthesis of the first mesoporous silica (150 Å) anchored carbohydrate-derived chiral ketone is described. This new heterogeneous catalyst has been shown to be effective in the asymmetric epoxidation of olefins by oxone.
Adam +60 more
core +1 more source
Carbohydrate-derived iminium salt organocatalysts for the asymmetric epoxidation of alkenes [PDF]
, 2014 A new family of carbohydrate-based dihydroisoquinolinium salts has been prepared and tested for potential as asymmetric catalysts for the epoxidation of unfunctionalized alkene substrates, providing up to 57% ee in the product ...
Adam +149 more
core +1 more source
Improvement of the Epoxide Hydrolase Properties for the Enantioselective Hydrolysis of Epoxides
Current Organic Chemistry, 2013 Peer ...
Solares, L. F., Mateo González, César
openaire +3 more sources
Oxidoperoxidomolybdenum(VI) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties [PDF]
, 2018 Oxidoperoxido–molybdenum(VI) complexes containing acylpyrazolonate ligands were obtained by reaction of [Mo(O)(O)2(H2O)n] with the corresponding acylpyrazolone compounds HQR.
Begines, Emilio +7 more
core +1 more source