A catalytic network embedding a formal rearrangement enables the first catalytic enantioselective multicomponent reaction (MCR) of sulfur ylides. In the presence of a bulky chiral phosphoric acid, the reaction combines sulfoxonium ylides, aldehydes and thiols, and affords synthetically versatile β‐hydroxy‐α‐sulfanyl carbonyl compounds in ...
Nicolò Santarelli +10 more
wiley +2 more sources
Function Meets Circularity: Metal-Ionomer Cross-Links Toughen and Recycle CO<sub>2</sub>‑Derived Polymers. [PDF]
Poon KC +4 more
europepmc +1 more source
AMPRO BIO/flax fiber composites with different fiber orientations fabricated by vacuum bagging for potential use in biomedical and automotive fields. ABSTRACT Replacing traditional thermoset resins with performing bio‐based alternatives plays a crucial role in the development of new sustainable composite materials.
Elisa Toto +4 more
wiley +1 more source
Lewis Acid-Catalyzed Alkylation of Azulene Derivatives with Epoxides and Oxetanes: A Regioselective Approach to Functionalized Azulene Alcohols. [PDF]
Brotons G +3 more
europepmc +1 more source
Graphene nanoplatelet (0.1 wt.%) reinforcement significantly enhances the performance of β Ti‐28Nb‐35.4Zr alloy. Grain refinement, reduced water contact angle, and improved surface characteristics promote osteoblast adhesion and complete surface coverage after 7 days.
Khurram Munir +5 more
wiley +1 more source
Exploring the synthesis of conduritol derivatives: strategies, challenges, and advances. [PDF]
Malik S, Mitra AK.
europepmc +1 more source
Light Metal Pyrazolates Grafted onto Periodic Mesoporous Silica for Carbon Dioxide Capture and Transformation. [PDF]
Kracht F +5 more
europepmc +1 more source
A Triple-Catalytic, Fully Biogenic Synthesis of Cyclic Carbonates. [PDF]
Stuhr R, Liu L, Jacobi von Wangelin A.
europepmc +1 more source
From SMILES Codes for Reactants and Products to Transition States With VeloxChem
Initial guesses for transition state optimizations are produced from a mere input of reactant and product SMILES codes, and achieved by interpolating generated force fields for reactants and products. The entire workflow scheme is implemented in the VeloxChem software.
Bastiaan van Hoorn +2 more
wiley +1 more source
Enantioselective Route to Terminal 2,3-Epoxy Tosylates Enabled by Cooperative Organocatalytic Desymmetrization of 2-Substituted Glycerol Derivatives. [PDF]
Astone A, Meninno S, Lattanzi A.
europepmc +1 more source

