Results 101 to 110 of about 12,831 (255)

A Unified Approach for the Synthesis of Conformationally Locked and sp2‐sp3 Fused Hybrids

open access: yesChemistry – A European Journal, EarlyView.
This study presents a systematic platform to build rigid sp2–sp3 hybrids via benzyne cycloadditions. Arene‑fused bicyclic oxa‐, aza‐, and carbocycles are converted into medicinally relevant amino acids and applied to Enalapril analogues synthesis. The hybrids combine aromatic interactions with 3D rigidity, tuning lipophilicity, pKa, and solubility ...
Ervis Saraci   +8 more
wiley   +1 more source

Partially Biobased Polyurethanes With Reversibly Crosslinkable Furan Units Toward Recyclable Thermosetting Textile Fibres

open access: yesChemistry – A European Journal, EarlyView.
A molecular design strategy combines lignin‐derived aromatic units, sugar‐derived furan groups, and flexible glycol segments to create wet‐spinnable polyurethanes. Thermally reversible Diels–Alder crosslinking chemistry enables formation of crosslinked thermosetting fibers, repeated de‐crosslinking/re‐crosslinking cycles, and tunable fiber properties ...
Rafael N. L. Menezes   +7 more
wiley   +1 more source

DETERMINACIÓN DE PRECURSORES DE DIOXINAS Y FURANOS DE LOS GASES PROCEDENTES DE UN INCINERADOR EN UN REACTOR FOTOCATALÍTICO

open access: yesRevista EIA
Se presenta un método cromatográfico para la determinación de dioxinas y furanos a partir de uno de sus precursores, tanto en estándares de medición como en muestras reales de gases tomadas en una empresa incineradora de Itagüí, Colombia.
Jorge Mario Giraldo, Aquiles Ocampo
doaj  

Redox‐Tuned Oxycarbamates Enable Divergent C─N and C─C Functionalization of Indolizines Under Photoredox Catalysis With Green Light

open access: yesChemistry – A European Journal, EarlyView.
Nonafluoromesitylsulfonyl (Nms)‐substituted oxycarbamates are introduced as redox‐lowered radical precursors for green‐light photoredox synthesis. Selective N─O bond cleavage generates amidyl radicals that directly aminate indolizines in DMF, whereas DMSO promotes 1,2‐hydrogen atom transfer (HAT) to α‐amino carbon‐centered radicals and C─C bond ...
Kevin Klaus Stefanoni, René Wilhelm
wiley   +1 more source

Microwave‐assisted catalytic pyrolysis of textile wastes: Synergistic effects and product characteristics

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract This study examines the microwave‐assisted catalytic pyrolysis (MACP) of individual and blended textiles (cotton, polyester, nylon 6) using ZnO and a ZnO/natural zeolite catalyst. In a custom‐built microwave reactor operated at 500°C, 1 kW power, and a 15‐min residence time, textile wastes were pyrolyzed.
Peyman Alizadeh   +3 more
wiley   +1 more source

Experimental methods in chemical engineering: The scientific method versus engineering design methodology

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Engineering graduate students confuse the scientific method and problem solving when presenting their pre‐doctoral exams and theses: Science discourse adopts question and hypotheses to assert and establish a study's rationale, while it is problem and objectives in engineering design.
Gregory S. Patience   +4 more
wiley   +1 more source

Synergistic Catalysis for Closed‐Loop Alcohol Refining: Concurrent H2 Evolution and Selective Oxidation

open access: yesEcoEnergy, EarlyView.
Photocatalytic, electrocatalytic, and photoelectrocatalytic systems exhibit a clear synergistic integration logic in closed‐loop alcohol refining—concurrently driving hydrogen evolution and selective alcohol oxidation to enable the directed conversion of alcohols into high‐value chemicals.
Wei Ren   +7 more
wiley   +1 more source

Morphology Engineering Derived CoOOH With Tunable Oxygen Vacancies for Potential‐Dependent Selective Electrooxidation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Through a morphology engineering strategy applied to CoFe PBA precursors, we successfully fabricated the CoOOH active phase enriched with oxygen vacancies and abundant edge sites. The introduced oxygen vacancies not only enhance the strong adsorption capacity for oxygen‐containing substrates but also suppress the overoxidation of HMFCA, thus enabling ...
Zhichen Liu   +8 more
wiley   +1 more source

Diels–Alder Versus Michael Adducts of 2‐Methylfuran and Maleate: Consecutive Synthetic Access to Both Product Types

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
More than a century after Albrecht's original proposal, an unexpected synthetic relationship between the historically misassigned Michael adduct type and the genuine Diels–Alder product is revealed. Experimental and theoretical studies show that the Michael adduct is not formed directly from the diene and dienophile, but instead arises through ...
Johanna Buddeberg   +3 more
wiley   +1 more source

The Furans. [PDF]

open access: yesJournal of the American Chemical Society, 1954
openaire   +2 more sources

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