Results 121 to 130 of about 39,482 (297)

Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†

open access: yesChinese Journal of Chemistry, EarlyView.
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley   +1 more source

Survey of sediment quality in Sabine Lake, Texas and vicinity [PDF]

open access: yes, 1999
The toxicity of sediments in Sabine Lake, Texas, and adjoining Intracoastal Waterway canals was determined as part of bioeffects assessment studies managed by NOAA’s National Status and Trends Program.
Anderson, Jack W.   +11 more
core  

Directed Hole Localization Stabilizing Interfacial Sulfur Species to Boost α‐C–H Activation for Selective Biomass Photo‐oxidation

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Efficient α‐C–H bond activation and directional conversion for selective biomass photo‐oxidation are achieved by integrating polarization and interface engineering strategies in P‐doped ZnIn2S4 polar photocatalysts, which leverage hole localization and stable interfacial sulfur species, endowing bio‐based HMF at 94.4% conversion with 94.5% selectivity ...
Yinyin He   +3 more
wiley   +1 more source

Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley   +1 more source

Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning

open access: yesGeophysical Research Letters
Furans are a major class of volatile organic compounds emitted from biomass burning. Their high reactivity with atmospheric oxidants leads to the formation of secondary organic aerosol (SOA), including secondary brown carbon (BrC) that can affect global ...
T. Joo   +6 more
doaj   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar   +3 more
wiley   +1 more source

Gap Analysis of Metabolic Conversions of Off-Flavors and Antinutrients in Plant-Based Substrates. [PDF]

open access: yesCompr Rev Food Sci Food Saf
ABSTRACT To drastically reduce the carbon footprint of the food production chain, a major shift towards alternatives to conventional meat and dairy products is required. The use of plant‐based proteins is a promising route, but it also comes with challenges: Plant‐based proteins often contain antinutritional factors and off‐flavors, which can ...
Kuijpers RI   +16 more
europepmc   +2 more sources

Greening Consumer Electronics: Moving Away From Bromine and Chlorine [PDF]

open access: yes, 2009
Presents case studies of seven electronics companies that have engineered environmental solutions that eliminate the use of most brominated and chlorinated chemicals that generate toxic materials.
Alexandra McPherson   +2 more
core  

Design and Synthesis of Lactose‐Derived Ligands and Their Application in Asymmetric Friedel–Crafts Alkylation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa   +2 more
wiley   +1 more source

Sustainable Microwave‐Enhanced Synthesis of 2‐Substituted Benzofurans From o‐Alkynylanisoles in Acidic Deep Eutectic Solvents

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A microwave‐enhanced sustainable and versatile approach to substituted benzofurans from 2‐alkynylanisoles enabled by an active Brønsted acidic deep eutectic solvent. The research on alternative media for organic transformations remains a highly demanding topic.
Alessandra Gritti   +9 more
wiley   +1 more source

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