Synthesis and Structural Characterization of Phosphanide Gold(III)/Gold(I) Complexes and Their Thallium(III) and Gold(III) Precursors [PDF]
Molecules, 2023 In this paper, we describe a series of diphenylphosphane and diphenylphosphanide gold(III) and gold(III)/gold(I) complexes containing 3,5-C6Cl2F3 as aryl ligands at gold that have been synthesized due to the arylating and oxidant properties of the new ...
Laura Coconubo-Guio +3 more
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Stable Pincer Gold(III)‐TADF Emitters with Extended Donor–Acceptor Separation for Efficient Vacuum‐Deposited OLEDs with Operational Lifetime (LT95) up to 3831 h at 1000 cd m−2 [PDF]
Advanced ScienceAlthough gold‐TADF (thermally activated delayed fluorescence) emitters have attractive prospects as next‐generation practical OLED emitters, the performance of OLEDs utilizing gold(I)‐ and gold(III)‐TADF emitters lags behind the requirements of practical
Hui‐Xing Shu +4 more
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Complexation of Gold(III) with Pyridoxal 5′-Phosphate-Derived Hydrazones in Aqueous Solution [PDF]
Molecules, 2022 Today, complexes of gold(I) and gold(III) are recognized as promising drugs for the treatment of bacterial infectious diseases and oncological diseases, respectively.
Natalia N. Kuranova +3 more
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Crystal structures of trichlorido(4-methylpiperidine)gold(III) and two polymorphs of tribromido(4-methylpiperidine)gold(III) [PDF]
Acta Crystallographica Section E: Crystallographic CommunicationsTrichlorido(4-methylpiperidine)gold(III), [AuCl3(C6H13N)], 1, crystallizes in Pbca with Z = 8. Tribromido(4-methylpiperidine)gold(III), [AuBr3(C6H13N)], 2, crystallizes as two polymorphs, 2a in Pnma with Z = 4 (imposed mirror symmetry) and 2b, which is ...
Cindy Döring, Peter G. Jones
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Organometallic gold(I) and gold(III) complexes for lung cancer treatment [PDF]
Frontiers in Pharmacology, 2022 Metal compounds, especially gold complexes, have recently gained increasing attention as possible lung cancer therapeutics. Some gold complexes display not only excellent activity in cisplatin-sensitive lung cancer but also in cisplatin-resistant lung ...
Juzheng Zhang +7 more
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Gold(III)-pyrrolidinedithiocarbamato Derivatives as Antineoplastic Agents [PDF]
ChemistryOpen, 2015 Transition metals offer many possibilities in developing potent chemotherapeutic agents. They are endowed with a variety of oxidation states, allowing for the selection of their coordination numbers and geometries via the choice of proper ligands ...
Brustolin, Leonardo +7 more
core +4 more sources
Crystal structures of seven gold(III) complexes of the form LAuX3 (L = substituted pyridine, X = Cl or Br) [PDF]
Acta Crystallographica Section E: Crystallographic CommunicationsThe structures of seven gold(III) halide derivatives of general formula LAuX3 (L = methylpyridines or dimethylpyridines, X = Cl or Br) are presented: trichlorido(2-methylpyridine)gold(III), [AuCl3(C6H7N)], 1 (as two polymorphs 1a and 1b); tribromido(2 ...
Cindy Döring, Peter G. Jones
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Steric and Electronic Effects in N-Heterocyclic Carbene Gold(III) Complexes: An Experimental and Computational Study [PDF]
Molecules, 2022 A series of neutral acridine-based gold(III)-NHC complexes containing the pentafluorophenyl (–C6F5) group were synthesized. All of the complexes were fully characterized by analytical techniques.
Miguel A. Rosero-Mafla +3 more
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Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)gold(III) tetrachloridoaurate(III)
Acta Crystallographica Section E, 2008 In the cation of the title compound, [AuCl2(C24H16N2)][AuCl4], the AuIII atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms.
Hamid Reza Khavasi +2 more
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Mechanochemical Gold(III)-Carbon Bond Formation. [PDF]
Angew Chem Int Ed Engl, 2021 AbstractStarting from a [(MeOC^N^C)AuCl] complex as precursor, a direct substitution by C,H‐activation from sp‐, sp2‐ or sp3‐C,H‐bonds under basic conditions in a planetary ball mill was achieved. Because of the extraordinary photophysical properties of the target compounds, this protocol provides an easy access to a highly valued complex class.
Eppel D +6 more
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