Ortho-nitrophenyl complexes of gold(III) [PDF]
Inorganica Chimica Acta, 1982 Many organogold complexes have been prepared using Grignard or organolithium reagents [l] , as well as organothallium [2] or organotin [3] complexes. We have recently shown that organomercury compounds can also be used for the synthesis of organogold(II1) complexes which are inaccessible through other routes [4].
José Vicente +3 more
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Gold(III)-CO and gold(III)-CO2 complexes and their role in the water-gas shift reaction [PDF]
, 2015 The water-gas shift (WGS) reaction is an important process for the generation of hydrogen. Heterogeneous gold catalysts exhibit good WGS activity, but the nature of the active site, the oxidation state, and competing reaction mechanisms are very much ...
Adelhelm +25 more
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Crystal structures of <i>trans</i>-di-bromido-bis-(4-picoline)gold(III) tetra-bromido-aurate(III) nitro-methane monosolvate, bis-(2-picolinium) tetra-bromido-aurate(III) bromide, and five salts of the type picolinium or lutidinium tetra-halogenidoaurate(III). [PDF]
Acta Crystallogr E Crystallogr CommunDöring C, Jones PG.
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Crystal structures of <i>trans</i>-di-bromido-bis-(3,5-lutidine)gold(III) tribromide and three 3,5-lutidinium salts containing tetra-bromido-aurate(III) anions (including three cases of polymorphism). [PDF]
Acta Crystallogr E Crystallogr CommunDöring C, Jones PG.
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Pharmaceutics, 2021 Bipyridine gold (III) dithiocarbamate compounds are Gold-III complexes with promising cytotoxic properties. In this study, the subacute toxicity of a Gold (III) complex with dithiocarbamate ligand was evaluated.
Ahmed Badar +5 more
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Biomedicines, 2021 Au2phen ((2,9-dimethyl-1,10-phenanthroline)2Au2(µ-O)2)(PF6)2 and Auoxo6 ((6,6′-dimethyl-2,2′-bipyridine)2Au2(µ-O)2)(PF6)2 are two structurally related gold(III) complexes that were previously reported to display relevant and promising anticancer ...
Giulia Gorini +7 more
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Gold(III) π‐Allyl Complexes [PDF]
Angewandte Chemie International Edition, 2019 AbstractGold(III) π‐complexes have been authenticated recently with alkenes, alkynes, and arenes. The key importance of PdII π‐allyl complexes in organometallic chemistry (Tsuji–Trost reaction) prompted us to explore gold(III) π‐allyl complexes, which have remained elusive so far.
Rodriguez, Jessica +5 more
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Luminescent cyclometalated gold(iii) complexes [PDF]
Dalton Transactions, 2011 Many luminescent gold(I) compounds are known, but in the vast majority of gold(III) complexes reported until recently, room temperature emission in fluid solution does not occur. As for other d(8) and d(6) metals, the key to obtaining gold(III) compounds with favorable luminescence properties seems to be the use of cyclometalating ligands that ensure ...
Bronner, Catherine, Wenger, Oliver S.
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Gold(III) Complexation in the Presence of the Macropolyhedral Hydridoborate Cluster [B20H18]2−
Inorganics, 2022 Gold(III) complexation with the octadecahydrido-eicosaborate anion [B20H18]2− was studied for the first time. It was found that when gold(III) complexes [Au(L)Cl2]BF4 (L = bipy, phen) reacted with [B20H18]2−, complexes [Au(L)Cl2]2[B20H18] were isolated ...
Varvara V. Avdeeva +6 more
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(Z)-5-Benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole
Molbank, 2023 By strategic use of the valence difference between hard gold(III) and soft gold(I) catalysts, one-pot synthesis of (Z)-5-benzylidene-4-phenyl-2-(p-tolyl)-4,5-dihydrooxazole (15) from propargylic alcohol (9) and p-toluamide (13) was achieved via gold(III)-
Nobuyoshi Morita +5 more
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