Biological evaluation of amidine derivatives: In vitro cytotoxicity and cellular antioxidant capacity. [PDF]
Pérez-Madrigal MM +9 more
europepmc +1 more source
Unraveling the Electron Transfer Mechanism in the Reduction of Bis(µ‐Oxido) Dicopper Complexes
We elucidate the electron transfer mechanism in bis(µ‐oxido) dicopper complexes stabilized by guanidine ligands. Kinetic and spectroscopic analyses reveal two sequential reduction steps without isomerization to µ‐η²:η²‐peroxido species. Marcus and density functional theory studies show ligand‐dependent reorganization energies and a unique two‐spin–four‐
Regina Schmidt +5 more
wiley +1 more source
Modification of the Zeolite Heulandite with N-(3-Triethoxysilylpropyl)guanidines Offers an Effective Approach to Enhancing Its Adsorption Capacity for Heavy Metal Ions. [PDF]
Adamovich SN +9 more
europepmc +1 more source
A Short Synthesis of Cyclo(‐RGDfK) Using a Microflow Reactor
An efficient synthesis of cyclo(‐RGDfK) was achieved by combining a one‐flow three‐component coupling (3CC) reaction via α‐amino acid N‐carboxy anhydrides with rapid macrolactamization using a microflow reactor. Precise control of the water content and base loading in the 3CC reaction enabled the gram‐scale synthesis of the desired tripeptides and ...
Naoto Yamasaki +6 more
wiley +1 more source
Guanidium Unmasked: Repurposing Common Amide Coupling Reagents for the Synthesis of Pentasubstituted Guanidine Bases. [PDF]
Aho JAS +4 more
europepmc +1 more source
Permanent chemical hair straightening was associated with analyte‐dependent changes in hair concentrations, showing increased endogenous GHB levels and decreased alprazolam concentrations after treatment. These results suggest that chemical hair straightening procedures may influence hair concentrations and should be considered when interpreting hair ...
Miriam Blanco‐Ces +5 more
wiley +1 more source
Positive Charge in an Antimalarial Compound Unlocks Broad-Spectrum Antibacterial Activity. [PDF]
Braun-Cornejo M +12 more
europepmc +1 more source
Stimuli‐Responsive Poly(Disulfide)s: A Versatile Platform for Intelligent Drug Delivery Systems
Ring‐opening polymerization based on dynamic disulfide bond exchange is an important method for synthesizing poly(disulfide)s. These polymers possess stimulus‐responsive mechanisms and show broad prospects in intelligent drug delivery. This review systematically discusses the ring‐opening polymerization strategy and research progress of drug delivery ...
Yuechen He +7 more
wiley +1 more source
Aluminum Cations Stabilized by Hybrid N-Heterocyclic Imine Ligand as Catalysts for Guanidine Synthesis from Carbodiimides and Anilines. [PDF]
Chang TW, Hung YF, Lin WY, Leung TF.
europepmc +1 more source

