Results 21 to 30 of about 25,792 (269)
Technical Note: Reactivity of C1 and C2 organohalogens formation – from plant litter to bacteria [PDF]
C1/C2 organohalogens (organohalogens with one or two carbon atoms) can have significant environmental toxicity and ecological impact, such as carcinogenesis, ozone depletion and global warming.
J. J. Wang +6 more
doaj +1 more source
Intramolecular halogen–halogen bonds?
By analysing the properties of the electron density in the structurally simple perhalogenated ethanes, X3C-CY3 (X, Y = F, Cl), a previously overlooked non-covalent attraction between halogens attached to opposite carbon atoms is found. Quantum chemical calculations extrapolated towards the full solution of the Schrödinger equation reveal the complex ...
Johansson, Mikael P., Swart, Marcel
openaire +5 more sources
Chemical, Electronic, and Electrical Properties of Alkylated Ge(111) Surfaces [PDF]
The use of Ge in semiconductor electronics has been constrained by the lack of a simple method of passivating the crystal surface. Toward that end, we have explored the utility of chemically bonded hydrocarbon monolayers.
Brunschwig, Bruce S. +2 more
core +2 more sources
Halogenation as a Strategy to Improve Antiplasmodial Activity: A Report of New 3-Alkylpyridine Marine Alkaloid Analogs [PDF]
Introduction: Due to the emergence of resistance to antimalarial drugs as well as the lack of vaccination for malaria, there is an urgent demand for the development of new antimalarial alternatives.
Camila Barbosa +6 more
doaj +1 more source
Selective C(sp2)−H Halogenation of "click" 4-Aryl-1,2,3-triazoles [PDF]
Selective bromination reactions of “click compounds” are described. Electron-neutral and electron-deficient arenes selectively undergo unprecedented Pd-catalyzed C–H ortho-halogenations assisted by simple triazoles as modular directing groups, whereas ...
Correa Navarro, Arkaitz +2 more
core +2 more sources
Insights into enzymatic halogenation from computational studies [PDF]
The halogenases are a group of enzymes that have only come to the fore over the last 10 years thanks to the discovery and characterization of several novel representatives.
Senn, Hans M.
core +2 more sources
A series of halogenated 1,5-diarylimidazole compounds were synthesized and their inhibitory effects on LPS-induced PGE2 production in RAW 264.7 cells were evaluated.
Zunhua Yang +4 more
doaj +1 more source
Enzymatic functionalization of carbon-hydrogen bonds [PDF]
The development of new catalytic methods to functionalize carbon–hydrogen (C–H) bonds continues to progress at a rapid pace due to the significant economic and environmental benefits of these transformations over traditional synthetic methods.
Arnold, Frances H. +2 more
core +1 more source
Halogen⋯halogen contra C–H⋯halogen interactions
Pressure affects the competition between C–H⋯X hydrogen bonds and X⋯X halogen⋯halogen interactions. In bromomethane, CH3Br, pressure changes the molecular arrangement of the two solid-state phases of this compound: low-pressure phase α is dominated by halogen⋯halogen interactions, whereas above 1.5 GPa the β phase is governed by C–H⋯halogen bonds.
Marcin Podsiadło +2 more
openaire +2 more sources
The present study focuses on the pyrolysis of discarded smartphone displays in order to investigate if a halogenation and volatilization of indium is possible without a supplementary halogenation agent.
Benedikt Flerus +4 more
doaj +1 more source

