Results 51 to 60 of about 31,763 (329)
Iron(III)-catalyzed chlorination of activated arenes [PDF]
A general and regioselective method for the chlorination of activated arenes has been developed. The transformation uses iron(III) triflimide as a powerful Lewis acid for the activation of N-chlorosuccinimide and the subsequent chlorination of a wide ...
Andrew Sutherland+8 more
core +1 more source
Decarboxylative Halogenation of Organic Compounds
Decarboxylative halogenation, or halodecarboxylation, represents one of the fundamental key methods for the synthesis of ubiquitous organic halides. The method is based on conversion of carboxylic acids to the corresponding organic halides via selective ...
A. Varenikov, E. Shapiro, Mark Gandelman
semanticscholar +1 more source
Synthesis and spectrometric study of some nucleophilic reactions of the antiepileptic molecule; 5,5-diphenyl imidazolidine-2,4-dione. [PDF]
New reaction routs were performed for the compound 5,5-diphenyl 2,4-imidazolidinedione (I) to give derivatives (II – VII). These reactions include acylation, halogenation, reduction, and nucleophilic substitutions. Most of the derivatives showed variable
Saadi M. D. Al-Nuzal+2 more
doaj +1 more source
Nontargeted biomonitoring of halogenated organic compounds in two ecotypes of bottlenose dolphins (Tursiops truncatus) from the Southern California Bight. [PDF]
Targeted environmental monitoring reveals contamination by known chemicals, but may exclude potentially pervasive but unknown compounds. Marine mammals are sentinels of persistent and bioaccumulative contaminants due to their longevity and high trophic ...
Aluwihare, Lihini I+8 more
core +3 more sources
Herein we report a general preparation of dihaloiodate salts of heterocyclic amines (tertiary and quaternary) with sterically accessible and hindered nitrogen atom.
Griša Grigorij Prinčič+3 more
doaj +1 more source
Asymmetric synthesis of gonytolide A: strategic use of an aryl halide blocking group for oxidative coupling [PDF]
The first synthesis of the chromanone lactone dimer gonytolide A has been achieved employing vanadium(V)-mediated oxidative coupling of the monomer gonytolide C. An o-bromine blocking group strategy was employed to favor para- para coupling and to enable
Iwata, Takayuki+5 more
core +1 more source
Microbial Halogenation With Specific Reference to Chiloroperoxidase
Microbial Halogenation With Specific Reference to ...
D.C Smith+5 more
doaj +1 more source
Halogenation as a tool to tune antimicrobial activity of peptoids
Antimicrobial peptides have attracted considerable interest as potential new class of antibiotics against multi-drug resistant bacteria. However, their therapeutic potential is limited, in part due to susceptibility towards enzymatic degradation and low ...
N. Molchanova+7 more
semanticscholar +1 more source
Synthesis and Characterization of Mixed Methyl/Allyl Monolayers on Si(111) [PDF]
The formation of mixed methyl/allyl monolayers has been accomplished through a two-step halogenation/alkylation reaction on Si(111) surfaces. The total coverage of alkylated Si, the surface recombination velocities, and the degree of surface oxidation as
Brunschwig, Bruce S.+3 more
core +1 more source
Non‐heme iron/α‐ketoglutarate dependent halogenases acting on freestanding substrates catalyze the regio‐ and stereoselective halogenation of inactivated C(sp3)‐H bonds.
A. Papadopoulou+6 more
semanticscholar +1 more source