Results 61 to 70 of about 7,061 (174)
ChemistryOpen, 2020 Screening for an interesting biocatalyst and its subsequent kinetic characterization depends on a reliable activity assay. In this work, a fluorometric assay based on the halogenation of 4‐methyl‐7‐diethylamino‐coumarin was established to monitor ...
Alexander V. Fejzagić +5 more
doaj +1 more source
Helvetica Chimica Acta, EarlyView.A data science framework integrating DFT featurization and hierarchical clustering was used to map the chemical space of over 2700 alkynes into six subsets before using experimental data for Ni3Zn‐catalyzed semihydrogenation and applying a logistic regression model to categorize substrates by reactivity.
Jordan De Jesus Silva +5 more
wiley +1 more source
Journal of Polymer Science, EarlyView.This review examines bio‐based polyurethanes from renewable feedstocks, focusing on structure‐property relationships governing mechanical performance. It analyzes reinforcement strategies, benchmarks against petrochemical counterparts, and explores future directions, including non‐isocyanate routes and circular economy integration for sustainable high ...
Khaled Chawraba +4 more
wiley +1 more source
Enhancing the Chemical Reactivity of Graphene through Substrate Engineering
Small, EarlyView.This review highlights methods to enhance the reactivity of graphene through substrate engineering, focusing on strain and charge doping. Strains induced by nanoparticles, metal crystal orientations, or stretchable polymers increase the reactivity of graphene.
Jia Tu, Mingdi Yan
wiley +1 more source
Molecules, 2016 The efficiency of direct conversion of tertiary alcohols bearing a β-hydrogen atom to vicinal halohydrins—chlorohydrins and bromohydrins—under green reaction conditions was tested preliminarily on model tertiary benzyl alcohols.
Njomza Ajvazi, Stojan Stavber
doaj +1 more source
A Platinum (II) Polyyne Oligomers Donor for Efficient Ternary Organic Solar Cells
Solar RRL, EarlyView.Platinum (II) polyyne oligomers P5 are used as a donor in a ternary organic solar cell. The average power conversion efficiency of 16% surpasses the international record for [Pt] (II) polyyne oligomers. PC71BM speeds up the rise time for electron transfer and slows down the recombination time.
Abdel Aziz Wayzani +10 more
wiley +1 more source
Olefin Polymerizations Oriented by Rational Designs of Group‐13 Compounds
The Chemical Record, EarlyView.In coordination olefin polymerization chemistry, boron and aluminum compounds play important roles in both catalyst components and monomers. This personal account introduces our recent progress on the development of catalyst systems featured by the design of group‐13 counteranions, as well as the application of boronic acid‐crosslinked polyolefins to ...
Ryo Tanaka, Yu Zou
wiley +1 more source
Deciphering the biosynthetic pathways of lichen acids
New Phytologist, EarlyView.Summary Depsides and depsidones are polyketide‐derived lichen acids widely distributed in lichen thalli, yet the biosynthetic gene clusters (BGCs) responsible for their production remain poorly understood. To address this gap, we investigated the diversity and evolutionary relationships of polyketide BGCs in lichens.
Wonyong Kim +11 more
wiley +1 more source
Stable BF2 Boracycles as Versatile Reagents for Selective Ortho C–H Functionalization
Angewandte Chemie, Volume 138, Issue 8, 16 February 2026.We report a robust, metal‐free and scalable synthesis of stable BF2 boracycles via directed ortho CH borylation, delivering isolable, shelf‐stable reagents without chromatographic purification. These BF2 boracycles exhibit unique and tunable reactivity, enabling highly selective ipso‐functionalization across a broad range of transformations.
Ganesh H. Shinde +11 more
wiley +2 more sources
Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene
Beilstein Journal of Organic Chemistry, 2016 The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the
Frederick J. Seidl, Noah Z. Burns
doaj +1 more source