Results 101 to 110 of about 27,695 (265)

From A Fundamental Study on Hydrogen Bond Network and Chain Mobility in Benzimidazole Model Compounds to Various Designs and Development of Benzimidazole-based Anhydrous Membranes for Proton Exchange Membrane Fuel Cell

open access: yesJournal of Analytical Science and Technology, 2011
A series of N-containing heterocycles i.e., imidazole and benzimidazole are systematically designed to study how proton transfer in anhydrous system is related to hydrogen bond network and molecular mobility.
Suwabun Chirachanchai   +2 more
doaj  

Asymmetric Fluorinated Spiro Hole‐Transport Materials Enabled by a Rapid Core‐Forming Strategy for Blade‐Coated Perovskite Solar Cells

open access: yesAdvanced Science, EarlyView.
Facile synthesis of asymmetric fluorinated spiro‐type HTMs combined with blade‐coating fabrication and vacuum‐assisted crystallization enables high‐efficiency PSCs with PCEs of 24.49% (0.09 cm2) and 23.28% (1.00 cm2), along with excellent stability.
Kun‐Mu Lee   +13 more
wiley   +1 more source

Beyond Conventional: A Review of Phytochemical‐Hydrogel Systems Enhanced by AI and 3D Printing for Chronic Wound Management

open access: yesAdvanced Science, EarlyView.
This review systematically bridges chronic wound pathology with natural phytochemical hydrogel therapeutics. A pathology‐to‐phytochemical mechanistic mapping framework is established, linking specific wound hallmarks to targeted phytochemical interventions.
Yitao Zhou   +8 more
wiley   +1 more source

Modular and Stereoselective Synthesis of Cyclobutane β‐Amino Alcohols

open access: yesAngewandte Chemie, EarlyView.
Late‐stage functionalization and photoisomerization of 1,2‐azaborine leads to a general strategy for the synthesis of diversely substituted cyclobutane β‐amino alcohols. The relative stereochemistry of the resulting products is unambiguously defined by the stereospecific and stereoselective nature of the photoisomerization‐hydrogenation‐oxidation ...
Xinyu Yang   +3 more
wiley   +2 more sources

1,7-Diazaspiro[5.5]undecane – A Neglected Heterocycle

open access: yes, 2016
A convenient and simple three step synthesis of 1,7-diazaspiro[5.5]undecane via Claisen condensation and acid catalyzed decarboxylation and spirocyclization of N-Boc-δ-valerolactam is described.
Philip R. D. Murray (1754782)   +3 more
core   +2 more sources

Continuous N-alkylation reactions of amino alcohols using γ-Al2O3 and supercritical CO2: unexpected formation of cyclic ureas and urethanes by reaction with CO2

open access: yesBeilstein Journal of Organic Chemistry, 2017
The use of γ-Al2O3 as a heterogeneous catalyst in scCO2 has been successfully applied to the amination of alcohols for the synthesis of N-alkylated heterocycles.
Emilia S. Streng   +3 more
doaj   +1 more source

Recent advances in heterocycle-based metal-free calamitics

open access: yes, 2017
The role of heterocycle-based calamitic liquid crystals has been investigated as potential candidates for photo-physical and opto-electronic applications.
Tapas Ghosh, Matthias Lehmann
core   +1 more source

Volatile Additives Engineering: A Trustworthy Morphology Control Strategy in Non‐Fullerene Organic Solar Cells

open access: yesAdvanced Science, EarlyView.
In this review, the classification and development history of the volatile solid and solvent additives are comprehensively summarized, the underlying mechanisms of morphology optimization are discussed, and a summary of volatile additive‐induced improvements in interfacial layer performance is provided.
Jianqiang Qin   +7 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

open access: yesAngewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang   +1 more
wiley   +2 more sources

Generative and Experimental Validation of High Refractive Index Polymers via Domain Knowledge Approach with Small Data

open access: yesAdvanced Intelligent Discovery, EarlyView.
This research demonstrates that the combination of domain knowledge–based multiple regression, multi‐objective Bayesian optimization, and generative models is a suitable prediction tool for candidates of high refractive index polymers, even with the constraints in the model trained on limited data. The experimental validation can reproduce the proposed
Takuya Yokoo   +3 more
wiley   +1 more source

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