Results 81 to 90 of about 28,367 (257)
A second polymorph of 3,4-bis(6-bromopyridin-3-yl)-1,2,5-thiadiazole
The title compound, C12H6Br2N4S, a second polymorph in the triclinic space group P-1, is presented. As in the earlier reported monoclinic polymorph in the space group C2/c [Becker et al. (2016). Chem. Eur. J. In the press], the thiadiazole ring is planar
Lisanne Becker +4 more
doaj +1 more source
Liquid‐Responsive Shape‐Memory Nanofiber‐Reinforced Scaffolds for Cartilage Repair
A liquid‐responsive shape‐memory, nanofiber‐reinforced QCG scaffold combines conformal defect filling, an aligned architecture that is structurally permissive for endogenous cell infiltration, and sustained KGN release. This integrated design enhances BMSC viability, migratory activity, and chondrogenic differentiation and promotes hyaline cartilage ...
Jiyang Zeng +8 more
wiley +1 more source
2-(3-Bromo-4-methoxyphenyl)-3-nitropyridine
The title compound, C12H9BrN2O3, was prepared in two steps from 2-chloro-3-nitropyridine. The nitrobiaryl unit is twisted, with dihedral angles of 35.4 (5)° between the nitro substituent and the pyridine ring to which it is bound, and 51.0 (5)° between ...
Daniel Limbach +2 more
doaj +1 more source
Elucidation of mechanisms and discovery of novel reactions are interconnected, as four research chapters from the Munich laboratory demonstrate. 1) In a new opening of the furan ring, 2-methoxyfuran and tetra-acceptor-substituted ethylenes furnish methyl acrylates, which are cis-3-substituted by a cyclopropyl ring that bears the four acceptor groups ...
openaire +3 more sources
Unlocking Li/Mg‐Based Photochemical Nitration Platforms for Anticancer Drug Discovery
Two low‐toxicity light main‐group metal photochemical systems based on lithium and magnesium are constructed for selective C(sp2)‐H (di)nitration of anilines. The obtained dinitrated products exhibit anti‐HCC (hepatocellular carcinoma) and anti‐KYSE30 cell activities, holding promise as novel antitumor candidates.
Qian Wan +13 more
wiley +1 more source
A new heterocycle 2-(3-methoxy-4-hexadecanoyloxyphenyl)benzothiazole was synthesized and its IR, 1H NMR, 13C NMR and MS spectroscopic data are presented.
Lay-Khoon Ong +3 more
doaj +1 more source
Statistical models for the prediction of the energy profile of H2 activation by silylenes and germylenes were developed. A simple model based on increments of the elements in α‐position enabled robust energy prediction, extrapolation to new structures, and transferability to new tetrylenes and substrates.
Michelle Kleinhaus +4 more
wiley +1 more source
3-Amino-6-ethoxy-4-phenyl-1H-pyrrolo[2,3-b]pyridine-2,5-dicarbonitrile
(Z)-2-(4-Chloro-5H-1,2,3-dithiazol-5-ylideneamino)-6-ethoxy-4-phenylpyridine-3,5-dicarbonitrile 1, when treated with either triphenylphosphine (4 equiv.) or polymer bound triphenylphosphine (5 equiv.) in dichloromethane at room temperature for 3 days ...
Sophia S. Michaelidou +1 more
doaj +1 more source
Ru-catalysed synthesis of fused heterocycle-pyridinones and -pyrones
The synthesis of fused heterocycle-pyridinones has been achieved by oxidative coupling of N-unprotected primary heterocycle-amides with internal alkynes.
Ruiz Morte, Sara +7 more
core +1 more source
The C3‐symmetric conjugate TASe, which integrates benzoselenadiazole, alanine, and acylhydrazone modules, self‐assembles into a chalcogen‐/hydrogen‐bonded porous framework in the solid state and uniform chiral nanospheres in aqueous media. These assemblies protect cardiomyocytes from doxorubicin‐induced oxidative injury by scavenging intracellular ...
Jinkui Teng +11 more
wiley +1 more source

