Results 151 to 160 of about 24,929 (273)

Three Component Thio‐ and Carboboration of Alkynes: A Modular Route to Functionalised Bicyclic Boronates

Angewandte Chemie, EarlyView.
Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey, Gary S. Nichol, Stephen P. Thomas, Dominic R. Willcox, Michael. J. Ingleson   +4 more
wiley   +2 more sources

Iron-Catalyzed Stereospecific Heterocycle N-Glycosylation with Glycal Epoxides. [PDF]

Org Lett
Zhang XW, Zhang D, Jiang Z, Xu H.
europepmc   +1 more source

π‐Extended COUPY Fluorophores for Targeted Near‐Infrared Fluorescence and Lifetime Imaging in Live Cells

Angewandte Chemie, EarlyView.
π‐Extended COUPY dyes, obtained by vinylogation of coumarin‐based COUPY scaffolds, shift absorption, and emission deep into the NIR region while preserving compactness and synthetic accessibility. These bright, photostable dyes enable live‐cell imaging, FLIM, and site‐specific peptide conjugation, offering a modular platform for targeted bioimaging and
Diego Abad‐Montero, Manel Bosch, Rodrigo Garcés‐Castellanos, Michael Q. Schottenhamel, Sergio Pedraza‐Arevalo, Alejandro Ibáñez‐Costa, Justo P. Castaño, Tania García‐Becerra, Elena Rebollo, Marta E. Alberto, Antonio Francés‐Monerris, Vicente Marchán   +11 more
wiley   +2 more sources

Novel Substituted Tetrahydropyrrolooxazolones as RIPK1 Inhibitors. [PDF]

ACS Med Chem Lett
Rong J, Liang SH.
europepmc   +1 more source

A Mononuclear Ruthenium(V)‐Imido Complex With Hydrogen Bonding in the Second Coordination Sphere Forming Aziridines Without N‐Substituents From Alkenes in Water

Angewandte Chemie, EarlyView.
This study employs a RuV═NH complex with hydrogen‐bonding (HB) sites in the SCS to afford non‐N‐substituted aziridines selectively. Nitrogen‐atom transfer occurs from the RuV═NH complex to alkenes in water to produce aziridine derivatives in high yields.
Tomoya Ishizuka, Chisato Ogawa, Yoshihito Shiota, Shunsuke Nozawa, Hiroaki Kotani, Shin‐ichi Adachi, Kazunari Yoshizawa, Takahiko Kojima   +7 more
wiley   +2 more sources

Radical Sampling Enabled Saturated N-Heterocycle Cyclization. [PDF]

J Am Chem Soc
Cai Q, Bissonnette NB, Kim S, Knauber T, Chinigo GM, Blakemore DC, MacMillan DWC.   +6 more
europepmc   +1 more source

Gold(III) Semiquinone Complexes: Synthesis, Structure, and Application in Photocatalysis

Angewandte Chemie, EarlyView.
Au(III) catecholate complexes engage into electron donor acceptor (EDA) interactions with aryldiazonium salts, enabling single‐electron transfer under green light irradiation. Ligand‐centered one‐electron oxidation to stable semi‐quinone complexes provides a new platform for standalone Au(III) photoredox catalysis, as substantiated by the C–H arylation
Miguel A. Gonzálvez, Félix Léon, Vlad Martin‐Diaconescu, Baptiste Martin, Sonia Mallet‐Ladeira, Juan José Gamboa‐Carballo, Karinne Miqueu, György Szalóki, Didier Bourissou   +8 more
wiley   +2 more sources

A photochemical strategy for pyrazole to imidazole conversion. [PDF]

Chem Sci
Wei Y, Kasama K, Igartua A, Yildiz DB, Ceuninck A, Dos Santos T, Büttner C, Thevenet D, Bossart M, Derdau V, Méndez M, Jubault P, Poisson T, Roure B, Leonori D.   +14 more
europepmc   +1 more source

Red-shifting squaraine dyes in the near-infrared region using perimidine heterocycles: synthesis and optical properties. [PDF]

RSC Adv
Sarasiya S, Henary M.
europepmc   +1 more source

Isolation of Base-Coordinated 1,4-Disilaquinones. [PDF]

Organometallics
Kelling L, Jörges M, Gessner VH.
europepmc   +1 more source