Endo or Exo? The first quantitative kinetic mapping of the nucleophilic reactivity of endo‐ and exo‐glycal compounds highlighted that endo‐glycals are typically 102 times less reactive than their corresponding parent cyclic enol ethers while exo‐glycals are 103 more nucleophilic. This experimental and computational structure–reactivity study highlights
Sophie Rodrigues +7 more
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Fused 3D boron heterocycles <i>via</i> EnT catalysis: synthesis, modification and validation as beta-lactamase inhibitors. [PDF]
Kortman HM +7 more
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Improving the Fidelity of Replication of a Six-Letter DNA Alphabet. [PDF]
Kim HJ +4 more
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Wavelength-dependent photofragmentation of pyrazine. [PDF]
Payra SS, Thakkar P, Lenka Y, Aravind G.
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Analysis of the structural diversity of heterocycles amongst European medicines agency approved pharmaceuticals (2014-2023). [PDF]
Ward M, O'Boyle NM.
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3-Component reactions for accessing heterocycle-rich topologies: trapping of pyrrole-stabilized carbenes <i>via</i> net bimolecular C-H or N-H insertion. [PDF]
Guzman AL, Toll KB, Hoye TR.
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Nanoparticle-Catalysed Microwave-Driven MCRs for Sustainable Heterocycle Synthesis. [PDF]
Kasi V +5 more
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The interplay of antiaromaticity and diradical character in diarenoindacenes and diindenoarenes. [PDF]
Vidal E, Warren GI, Barker JE, Haley MM.
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Transfer Learning for Heterocycle Retrosynthesis. [PDF]
Wieczorek E +9 more
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Accelerated and Green Synthesis of <i>N,S</i>- and <i>N,O</i>-Heterocycles in Microdroplets. [PDF]
Ghosh J +3 more
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