Results 241 to 250 of about 128,452 (331)

Enhanced CO2 Electroreduction Through Electrostatic Functionalization of Iron Porphyrin

open access: yesChemCatChem, EarlyView.
This study introduces an iron porphyrin catalyst for CO2 reduction, featuring an ortho‐positioned imidazolium group designed to probe electrostatic effects. The catalyst exhibits a 100‐fold increase in activity over its unsubstituted counterpart at similar potentials.
Adrien Smith   +3 more
wiley   +1 more source

Metal‐Free Covalent Organic Frameworks for Photocatalytic CO2 Reduction

open access: yesChemistryEurope, EarlyView.
This review presents an environmentally sustainable strategy to address the critical issue of escalating atmospheric CO2 levels. It explores the application of metal‐free covalent organic frameworks in a photocatalytic approach, offering a green and efficient strategy for carbon dioxide reduction and contributing to climate change mitigation.
Supriti Dutta   +3 more
wiley   +1 more source

HCl-mediated silylation of C-H bonds in (hetero)arenes with trialkylsilanes. [PDF]

open access: yesChem Sci
Su Y   +6 more
europepmc   +1 more source

Synthesis and Characterization of π‐Extended Azulenes via Nucleophilic Substitution and Intramolecular Cyclization of 5‐Alkynyl‐6‐Fluoroazulenes

open access: yesChemistryEurope, EarlyView.
A modular synthetic approach enables the preparation of azulene‐fused heterocycles via nucleophilic aromatic substitution followed by intramolecular cyclization of alkynyl fluoroazulenes. The method allows the incorporation of various heteroatoms (N, O, S, Se, and Te), leading to structurally diverse heteroannulated azulenes.
Martin C. Dietl   +8 more
wiley   +1 more source

Easier, Safer, and Greener: Unlocking the Power of Solid Reagents in Organic Reactions by Mechanochemistry

open access: yesChemistryEurope, EarlyView.
This review highlights the powerful synergy between mechanochemistry and solid reagents to replace hazardous substances traditionally used in organic synthesis. Such an approach offers a safer and more sustainable pathway for conducting organic reactions, with potential benefits in both reactivity and selectivity. The use of solid bases, acids, and gas
Adrien Gallego   +4 more
wiley   +1 more source

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