Results 251 to 260 of about 128,452 (331)

Redox‐Active Frustrated Lewis Pair‐Mediated B─H Bond Activation: From Proton Transfer to THF Ring Opening

open access: yesChemistryEurope, EarlyView.
Carbene‐stabilized dithiolene zwitterion, as a redox‐active frustrated Lewis pair, can mediate the B─H bond activation of catecholborane via hydride‐coupled reverse electron transfer processes. This discovery represents the first experimental evidence of the FLP‐mediated B─H activation via net proton transfer.
Yuzhong Wang   +5 more
wiley   +1 more source

Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications

open access: yesChemistryEurope, EarlyView.
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang   +6 more
wiley   +1 more source

Nitrone chemistry: a versatile gateway to diverse heterocycles. [PDF]

open access: yesRSC Adv
Mohapatra S   +4 more
europepmc   +1 more source

Hydrogen Bonding is Key Factor in Reversible NH3 Uptake Causing Vapochromic and Magnetochemical Switching in Ni(II) Paddlewheel Complexes

open access: yesChemistryEurope, EarlyView.
Nickel complexes showing reversible vapochromic and spin crossover behaviors upon coordination and release of NH3 were synthesized. They bear bidentate pyridazine ligands, which allows for formation of hydrogen bonds between NH3 and the ligand in the second coordination sphere.
Sebastian Rücker   +7 more
wiley   +1 more source

Advances in Parahydrogen‐Induced Polarization for Nuclear Magnetic Resonance of Peptides, Proteins, and Biopolymers

open access: yesChemistryEurope, EarlyView.
Hyperpolarization by parahydrogen‐induced polarization enhances the sensitivity of nuclear magnetic resonance spectroscopy of amino acids, peptides, mini‐proteins, and biopolymers using nonnatural amino acids with unsaturated side chains up to three orders of magnitude.
Gerd Buntkowsky
wiley   +1 more source

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