Results 281 to 290 of about 169,803 (413)

Organopalladium(II) Complexes Containing Carbon-Bonded Heterocycles as a Ligand [PDF]

open access: bronze, 1986
Kiyoshi Isobe   +3 more
openalex   +1 more source

PPh3/Isocyanide and N2/Isocyanide Exchange: Pathways to Isolable Alkali Metal Keteniminyl Anions

open access: yesAngewandte Chemie, EarlyView.
The synthesis of isolable keteniminyl anions through substitution of the phosphine ligand in metalated ylides or the N₂ ligand in diazomethanides with isocyanides is reported. The anions feature a bent geometry, with the angle decreasing with increasing donor ability of the nitrogen substituent, and exhibit broad applicability in the formation of ...
Sunita Mondal   +7 more
wiley   +1 more source

Site‐Selective Carbonylation of Azetidines via Copper‐Catalyzed Difluorocarbene Insertion

open access: yesAngewandte Chemie, EarlyView.
We disclose a site‐selective Cu‐catalyzed carbonylation of azetidines promoted by difluorocarbene insertion at low temperature, enabling access to a variety of functionalized γ‐lactams and a therapeutic agent for diabetes (40 examples). This skeletal expansion strategy provides a distinct disconnection approach to synthesize medicinally relevant five ...
Fang Zhou, Tong‐De Tan, Ming Joo Koh
wiley   +1 more source

Formaldehyde surrogates in multicomponent reactions. [PDF]

open access: yesBeilstein J Org Chem
Attorresi CI, Ramírez JA, Westermann B.
europepmc   +1 more source

Isolable Three‐Coordinate Base‐Stabilized Alumylene: A Precursor of Persistent Acceptor‐Free Monomeric Aluminum Oxide

open access: yesAngewandte Chemie, EarlyView.
A monomeric alumylene stabilized by two donor ligands (phosphine and NHC) has been successfully synthesized. This alumylene complex exhibits an enhanced nucleophilic character and a preserved ambiphilic reactivity compared to the monoligated complex. As a consequence, its oxidation by N2O proceeds even at −90 °C, allowing the synthesis of an acceptor ...
José Miguel León Baeza   +8 more
wiley   +1 more source

Molecular Design by Cycloaddition Reactions of Heterocycles with Some Dienophiles

open access: gold, 1974
Tadashi Sasaki   +4 more
openalex   +1 more source

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