Synthesis of 1,4-Disubstituted Mono and Bis-triazolocarbo-acyclonucleoside Analogues of 9-(4-Hydroxybutyl)guanine by Cu(I)-Catalyzed Click Azide-Alkyne Cycloaddition [PDF]
A series of novel mono-1,2,3-triazole and bis-1,2,3-triazole acyclonucleoside analogues of 9-(4-hydroxybutyl)guanine was prepared via copper(I)-catalyzed 1,3-dipolar cycloaddition of N-9 propargylpurine, N-1-propargylpyrimidines/as-triazine with the ...
Engels, Joachim W.+2 more
core +2 more sources
Surface Coordination and Polymerization of Allyl Mercaptan Passivates the Oxidation of Copper
This study demonstrates that allyl mercaptan self‐assembles on the surface of copper via coordination and polymerization, forming an ultrathin polymeric passivation layer (8.06 ± 0.50 nm). The modified copper foil achieves a two‐order‐of‐magnitude anti‐corrosion performance enhancement across multi‐service environments. Abstract The oxidation of copper
Jiahao Yang+5 more
wiley +1 more source
Thermally Stimulated Luminescence and Current in new heterocyclic materials for Organic field transistors and organic light emitting diodes [PDF]
The present work is focused on theoretical and experimental study of localised levels in organic materials suitable for light-emitting devices and field effect transistors by means of thermal techniques. In our work we focused on low molecular compounds as well as on polymers, especially of two classes of materials: oxadiazoles and quinoxalines.
arxiv
Heme iron from meat and risk of colorectal cancer: a meta-analysis and a review of the mechanisms involved [PDF]
Red meat and processed meat intake is associated with a risk of colorectal cancer, a major cause of death in affluent countries. Epidemiological and experimental evidence supports the hypothesis that heme iron present in meat promotes colorectal cancer ...
Bingham+24 more
core +3 more sources
Complexes [PtII(Cbz‐C^C*bzim/im)(L^L)], bearing carbazole‐appended cyclometalated NHCs, show bright phosphorescence, peaking from the blue to the yellowish–green spectral range depending on the carbene, L^L, and doping concentration. Non‐doped OLEDs using 1A or 3A (L^L = acac or P^O2) reach the best performances (Von: 2.99 V, 2.55 V; Lmax: 39208, 25837
Jorge Roy+9 more
wiley +1 more source
Hyperphosphorescent OLEDs: Harnessing the Power of MR‐TADF Terminal Emitters
Hyperphosphorescent organic light‐emitting diodes (HP‐OLEDs) use phosphorescent sensitizers with multiresonant thermally activated delayed fluorescence terminal emitters. HP‐OLEDs show efficient, narrowband electroluminescence and moderate efficiency roll‐off.
Emma V. Puttock+3 more
wiley +1 more source
Methods for the synthesis of polyhydroxylated piperidines by diastereoselective dihydroxylation: Exploitation in the two-directional synthesis of aza-C-linked disaccharide derivatives [PDF]
Background: Many polyhydroxylated piperidines are inhibitors of the oligosaccharide processing enzymes, glycosidases and glycosyltransferases. Aza-C-linked disaccharide mimetics are compounds in which saturated polyhydroxylated nitrogen and oxygen ...
Adam Nelson+8 more
core +3 more sources
Recent Progress in Organic TADF Emitters Containing Heavy Atoms
In this review, progress on heavy atom use in organic TADF emitters to produce internal and external heavy atom effects is summarized. Impacts on molecular geometry, TADF efficiency, and performance in OLEDs are discussed. An outlook on the challenges and opportunities of heavy atom incorporation is provided.
Seja A. Elgadi+2 more
wiley +1 more source
Minor groove binders: some recent research in drug development [PDF]
The role of the naturally occurring polyamides distamycin and netropsin as antibacterial agents is described. Also, the importance of the modifications to the lipophilic and hydrophobic moieties is discussed.
Khalaf, Abedawn I.
core
Abstract Photochemical C−C coupling reactions can be tailored to industrial chemical processes and preparations of pharmaceuticals. Recent approaches in this area are limited to using precious transition metal coordination complexes that facilitate light absorption and redox processes with benchtop chemicals. Herein, we propose a paradigm that involves
Samjhana Maharjan+9 more
wiley +1 more source