Results 41 to 50 of about 191,930 (359)

Ligand relay catalysis for cobalt-catalyzed sequential hydrosilylation and hydrohydrazidation of terminal alkynes

open access: yesNature Communications, 2022
In organic chemistry, performing sequential catalytic cycles with a single catalyst improves efficiency. Here the authors present a methodology to functionalize alkynes with nitrogen and silicon atoms, through two catalytic cycles with a homogeneous ...
Yufeng Sun   +3 more
doaj   +1 more source

Identification of single-site gold catalysis in acetylene hydrochlorination [PDF]

open access: yes, 2017
There remains considerable debate over the active form of gold under operating conditions of a recently validated gold catalyst for acetylene hydrochlorination.
Catlow, C. Richard A.   +14 more
core   +4 more sources

Class IIa HDACs forced degradation allows resensitization of oxaliplatin‐resistant FBXW7‐mutated colorectal cancer

open access: yesMolecular Oncology, EarlyView.
HDAC4 is degraded by the E3 ligase FBXW7. In colorectal cancer, FBXW7 mutations prevent HDAC4 degradation, leading to oxaliplatin resistance. Forced degradation of HDAC4 using a PROTAC compound restores drug sensitivity by resetting the super‐enhancer landscape, reprogramming the epigenetic state of FBXW7‐mutated cells to resemble oxaliplatin ...
Vanessa Tolotto   +13 more
wiley   +1 more source

Mass transfer in gas-liquid slurry reactors [PDF]

open access: yes, 1993
A critical review is presented on the mass transfer characteristics of gas¿liquid slurry reactors. The recent findings on the influence of the presence of solid particles on the following mass transfer parameters in slurry reactors are discussed ...
Beenackers, A.A.C.M., Swaaij, W.P.M. van
core   +6 more sources

Transient Operation of a Perovskite Partially Coated Monolith at High Pressure

open access: yesChemical Engineering Transactions, 2015
This work deals with the experimental study of transient ignition during high-pressure combustion of CH4- enriched syngas. The structured catalyst is a monolith where only the external channels are coated with 20 wt.
P. Barbato   +3 more
doaj   +1 more source

Catalytic evaluation of citrate-stabilized palladium nanoparticles in the Sonogashira reaction for the synthesis of 1,4-Bis[(trimethylsilyl)ethynyl]benzene

open access: yesCatalysis Communications, 2021
Citrate-stabilized palladium nanoparticles were synthesized and supported on silica spheres. Conditions affecting particle size, stability and adsorption on silica particles are explored.
Erick Gálvez-Martínez   +4 more
doaj   +1 more source

Catalytic polymeric nanoreactors : more than a solid supported catalyst [PDF]

open access: yes, 2012
Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell.
Bosman, Liu, Wang, Yan
core   +2 more sources

Rethinking plastic waste: innovations in enzymatic breakdown of oil‐based polyesters and bioplastics

open access: yesFEBS Open Bio, EarlyView.
Plastic pollution remains a critical environmental challenge, and current mechanical and chemical recycling methods are insufficient to achieve a fully circular economy. This review highlights recent breakthroughs in the enzymatic depolymerization of both oil‐derived polyesters and bioplastics, including high‐throughput protein engineering, de novo ...
Elena Rosini   +2 more
wiley   +1 more source

Organoplatinum (II) complexes containing bis-(N-heterocyclic carbene) ligands: Catalytic activity in hydrosilylation of α,β-unsaturated ketones [PDF]

open access: yesشیمی کاربردی روز, 2018
Two N-heterocyclic carbene platinum complexes [PtMe2(NHC)], 1 and [Pt(TFA)2(NHC)], 2, in which, NHC = 1, 1′- methylene- 3, 3′- bis[(N-(tert-butyl) imidazol-2- ylidene] have been prepared and characterized using NMR spectroscopy and ESI-MASS spectrometry.
sirous jamali, Sedigheh Abedanzadeh
doaj   +1 more source

Direct methane conversion to methanol by ionic liquid-dissolved platinum catalysts [PDF]

open access: yes, 2006
Ternary systems of inorganic Pt salts and oxides, ionic liquids and concentrated sulfuric acid are effective at catalyzing the direct, selective oxidation of methane to methanol and appear to be more water tolerant than the Catalytica ...
Cheng, Jihong   +3 more
core   +2 more sources

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