Results 71 to 80 of about 191,930 (359)

Oxidative desulfurization of diesel fuel oil using supported Fenton catalysts and assisted with ultrasonic energy

open access: yesPetroleum Science, 2019
An ultrasound-assisted heterogeneous catalytic oxidation process was applied to eliminate sulfur from commercial diesel fuel oil. The studied variables were catalyst concentration, type of catalyst (homogeneous or heterogeneous), oxidizing agent ...
Roberto Flores   +2 more
doaj   +1 more source

Clean synthesis of adipic acid from cyclohexene in microemulsions with stearyl dimethyl benzyl ammonium chloride as surfactant: From the laboratory to bench scale [PDF]

open access: yes, 2012
Adipic acid, HOOC(CH2)4COOH, is a white crystalline solid used primarily in the manufacture of nylon-6,6 polyamide. In industry, adipic acid is mainly produced by oxidation of cyclohexane with air and nitric acidfollowing a homogeneous two-step route ...
Cognet, Patrick   +3 more
core   +3 more sources

Cu‐Based MOF/TiO2 Composite Nanomaterials for Photocatalytic Hydrogen Generation and the Role of Copper

open access: yesAdvanced Functional Materials, EarlyView.
HKUST‐1/TiO2 composite materials show a very high photocatalytic hydrogen evolution rate which increases as a function of the irradiation time until reaching a plateau and even surpasses the performance of the 1%Pt/TiO2 material after three photocatalytic cycles.
Alisha Khan   +9 more
wiley   +1 more source

Process intensification for continuous synthesis of performic acid using Corning advanced-flow reactors

open access: yesGreen Processing and Synthesis, 2017
The present paper reports the experimental details for the synthesis of performic acid (PFA) using Corning advanced-flow reactors (AFRs) using formic acid and H2O2 as reactants, and sulfuric acid as homogeneous catalyst. The effect of different operating
Gaikwad Shekar M.   +9 more
doaj   +1 more source

Synthesis of (Ind)2ZrCl2 Catalyst for Copolymerization of Ethylene and Propylene: Parameters Effect on Productivity [PDF]

open access: yesعلوم و تکنولوژی پلیمر, 2010
Bis(indenyl)zirconium dichloride as a catalyst was synthesized using a modified method at the room temperature. Polymerization of ethylene and copolymerization of ethylene and propylene were carried out by this metallocene catalyst. Ethylene propylene (P/
S. Ahmadjo   +4 more
doaj   +1 more source

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

Synthesis of biscoumarin derivatives by the reaction of aldehydes and 4-hydroxycoumarin using ruthenium (III) chloride hydrate as a versatile homogeneous catalyst [PDF]

open access: yesJournal of the Serbian Chemical Society, 2012
The one-pot domino Knoevenagel-type condensation/Michael reaction of aromatic, heteroaromatic and aliphatic aldehydes with 4-hydroxycoumarin in aqueous media in the presence of ruthenium salt as homogeneous catalyst was investigated. It was found that
Tabatabaeian Khalil   +4 more
doaj   +1 more source

Active colloids at fluid interfaces

open access: yes, 2016
If an active Janus particle is trapped at the interface between a liquid and a fluid, its self-propelled motion along the interface is affected by a net torque on the particle due to the viscosity contrast between the two adjacent fluid phases.
Dietrich, S.   +2 more
core   +1 more source

Model arenes hydrogenation with silica-supported rhodium nanoparticles:The role of the silica grains and of the solvent on catalytic activities [PDF]

open access: yes, 2009
Silica-supported rhodium-based nanoheterogeneous catalysts were easily prepared by impregnation with a pre-stabilized colloidal suspension. The resulting catalysts contain rhodium nanoparticles well-dispersed in the silica pores with a mean size of 5 nm.
Barthe, Laurie   +5 more
core   +4 more sources

Copper Doping Enhances the Activity and Selectivity of Atomically Precise Ag44 Nanoclusters for Photocatalytic CO2 Reduction

open access: yesAdvanced Functional Materials, EarlyView.
By a simple anti‐Galvanic reaction, up to six copper atoms could be preferably doped into the Ag2(SR)5 staple motifs and Ag20 dodecahedral shell of an atomically precise Ag44(SR)30 nanocluster. When anatase TiO2 is used as substrate, the (AgCu)44/TiO2 photocatalyst exhibited much improved activity in photocatalytic CO2 reduction compared to Ag44/TiO2 ...
Ye Liu   +5 more
wiley   +1 more source

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