It's a Gas: Bioconjugation With Vapor‐Phase Reagents
Gaseous reagents are an emerging class of bioconjugation reagents that can offer alternative selectivity paradigms for the construction of precise bioconjugates. A variety of both inert and highly reactive gases have recently been developed for bioconjugation use.
Yuxuan Ding, Jun Ohata, Zachary T. Ball
wiley +1 more source
A chemical bonding based descriptor for predicting the role of anharmonicity induced by quantum nuclear effects in hydride superconductors. [PDF]
Belli F, Zurek E, Errea I.
europepmc +1 more source
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich +9 more
wiley +1 more source
Ab initio analysis of the structural, hydrogen storage, mechanical, electronic, and optical characteristics of Cs<sub>2</sub>XAlH<sub>6</sub> (X = K, Na, Rb) double perovskite hydrides. [PDF]
Al-Qawasmeh A +4 more
europepmc +1 more source
The mechanism of pacifigorgiadiene synthase from Burkholderia gladioli was investigated through isotopic labeling experiments and DFT calculations. The results revealed an unexpected labeling pattern which appeared to be different in the main and the side products, requiring unprecedented mechanistic explanations, including a “break‐flip‐cyclise ...
Zhiyong Yin +6 more
wiley +1 more source
One-Dimensional Hydrogen Chains in Li-Hf-H System: A Pathway to High Superconductivity Under High Pressure. [PDF]
Yang K +9 more
europepmc +1 more source
Asymmetric Reduction of Unactivated Alkenes
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner +3 more
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Decomposition Dynamics of a New Noble-Gas Compound. [PDF]
Cohen A, Gerber RB.
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Abstract The synthesis and characterization of an amphiphilic nitroxide to be used as a controlling agent in a nitroxide‐mediated living radical polymerization in aqueous dispersion media is presented. In the first stage of nitroxide synthesis (phthalimide protection), two reaction methods were employed: traditional and microwave.
Enrique García‐Leal +3 more
wiley +1 more source
Excellent hydrogen storage capabilities and optoelectronic attributes of XClH<sub>6</sub> (Li, Na, and K) perovskite hydrides for green energy technologies. [PDF]
Murtaza H +6 more
europepmc +1 more source

