Results 161 to 170 of about 11,727 (238)

Additives Promote Divergent Reactivity in Photolytic Deoxygenation and Lactonization Reactions of Cobalt Alkoxycarbonyls

European Journal of Organic Chemistry, EarlyView.
We report a carbonylation‐homolysis process to access acyl radicals that can undergo decarboxylation or cyclization onto tethered alkenes. In both cases, ligands and additives are shown to influence the outcome to give saturated or unsaturated products, in some cases with isomerization of the initial products.
Jacob N. Hackbarth, Dana R. Chambers, Cory T. Ludwig, Tyler K. Brown, David B. C. Martin   +4 more
wiley   +1 more source

Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]

Chem Sci
Ochs J, Metzler-Nolte N.
europepmc   +1 more source

Synthesis of Sulfur Heterocycles by Palladium‐Catalyzed Cyclization

European Journal of Organic Chemistry, EarlyView.
In spite of the well‐known palladium thiophilicity, sulfur‐containing acyclic substrates may efficiently undergo several different kinds of palladium‐catalyzed cyclization processes leading to highly important sulfur heterocycles in one synthetic step. Advances in this challenging and stimulating field of research are presented in this review.
Bartolo Gabriele
wiley   +1 more source

First-principle study on superconductivity of metastable MoH₉ and MoH₁₂ under high pressure. [PDF]

iScience
Yan X, Huang H, Song H, Duan D, Du M, Cui T, Wei X.   +6 more
europepmc   +1 more source

Hydride-Ion Conduction in Perovskite Hydride SrLiH3

Hydride-Ion Conduction in Perovskite Hydride SrLiH3
identifier:oai:t2r2.star.titech.ac.jp ...
openaire  

Transfer Hydrogenation of Organic Azides to Amines by Ammonia Borane Complex Under Mild Conditions Catalyzed by Reusable Au Nanoparticles

European Journal of Organic Chemistry, EarlyView.
Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda, Dimitra Malliotaki, Ioannis Zachilas, Andreas‐Drakos Kokkinos, Orestis Agathocleous, Manolis Stratakis   +5 more
wiley   +1 more source

Hydrogen storage performance of Ti_0.75Zr_0.25Mn_0.9CrFe_0.1 alloy with different preparation methods. [PDF]

RSC Adv
Mu Y, Zhou Y, Yang G, Xu L, Xu H, Zhu L, Han X, Chu X, Liu W, Lv L.   +9 more
europepmc   +1 more source

Enzymatic Synthesis of Demethylated Sesquiterpenes From 14‐nor‐Farnesyl Pyrophosphate

European Journal of Organic Chemistry, EarlyView.
The substrate analog 14‐nor‐FPP was synthesised and enzymatically converted with 10 bacterial and fungal sesquiterpene synthases, resulting in the isolation of 12 demethylated sesquiterpenes in yields up to 17%. In most cases the demethyl analogs of the FPP‐derived natural products were obtained, but also different products showing modified ...
Kizerbo A. Taizoumbe, Jeroen S. Dickschat   +1 more
wiley   +1 more source

Hydride Accessibility and Reactivity in the Configurational and Stoichiometric Space of β-Ga₂O₃ for CO₂ Hydrogenation. [PDF]

J Phys Chem Lett
Baidun MS, Kolganov AA, Alexandrova AN, Pidko EA.   +3 more
europepmc   +1 more source

Silyl Rearrangements in Gold‐Catalyzed Transformations

European Journal of Organic Chemistry, EarlyView.
The synergy between the exceptional ability of gold catalysts to activate unsaturated substrates and the inherent tendency of organosilicon reagents to undergo silyl‐group rearrangements has unlocked a range of novel transformations, enabling access to otherwise challenging molecular architectures.
Patricia García‐Martínez, Luis A. López   +1 more
wiley   +1 more source