Results 61 to 70 of about 1,209 (177)

Study on catalysts and reaction process for highly selective hydroformylation of 1-octene

open access: yes上海师范大学学报. 自然科学版
Using rhodium dicarbonylacetylacetonate as the rhodium(Rh) catalyst precursor, the catalytic performances of different monodentate and bidentate phosphine ligands, bisphosphite ligands, and the self-synthesized ligand system Rh-L9 were investigated in ...
YANG Xushi   +5 more
doaj   +1 more source

Synthesis of (–)-Indolizidine 167B based on domino hydroformylation/cyclization reactions

open access: yesBeilstein Journal of Organic Chemistry, 2008
The synthesis of (–)-Indolizidine 167B has been achieved from optically active (R)-3-(pyrrol-1-yl)hex-1-ene. The key step is a highly regioselective hydroformylation reaction and a one-pot intramolecular cyclization providing a general approach to the ...
Giuditta Guazzelli   +2 more
doaj   +1 more source

Effect of by-products from hydroformylation of isobutene on reaction

open access: yes上海师范大学学报. 自然科学版, 2018
The applications of isovaleraldehyde and the types of isobutene hydro-formylation catalysts were simply described. The effect of by-products from the hydroformylation of isobutene such as isoamyl alcohol, isovaleric acid, and isobutane, on the yield and ...
SUN Yanan   +3 more
doaj   +1 more source

Hydroformylation of Limonene

open access: yesJournal of Japan Oil Chemists' Society, 1973
Hydroformylation of limonene has been studied using cobalt carbonyl and rhodium carbonyl catalysts under “oxo reaction” conditions. The aimed β- (4-methyl-Δ3-cyclohexenyl) -butylaldehyde was obtained with theoretical yields of 42 and 52% based on limonene by using bis- (cobalt tricarbonyl tributylphosphine) complex and rhodium carbonyl catalysts ...
KOGAMI, Kunio   +3 more
openaire   +2 more sources

Synthesis, characterization and Hydroformylation Catalytic Activity of 1-hexene of Water-soluble RuCl2(DMSO)2(PySO3Na)2 Complex [PDF]

open access: yesAvances en Química, 2012
In this work we describe the synthesis and characterization of a new water soluble ruthenium complex [Ru(Cl)2(DMSO)2(PySO3Na)2] (complex 1); where [PySO3Na] is the sodium salt of p-sulphonated pyridine.
Yuraima Fonseca   +6 more
doaj  

Olefin hydroformylation catalysis with RuCl2(DMSO)4. [PDF]

open access: yesAvances en Química, 2008
The RuCl2(DMSO)4 complex was used as catalytic precursor in olefin hydroformylation reactions, giving good percent yield and better selectivity for linear aldehydes.
Marisela Reyes*   +9 more
doaj  

Study on Preparation of Mesoporous MCM-41 Zeolite Supported HRh(CO)(PPh3)3 Complex for Isobutene Hydroformylation

open access: yes工程科学与技术, 2007
:The mesoporous molecular sieves Si-MCM-41 was synthesized by hydrothermal method, and the catalysts supported the HRh(CO)(PPh3)3 on the Si-MCM-41 material were prepared. The proper parameters of the Si-MCM-41carrier synthesis were investigated.
doaj  

Organophotoredox/Cobalt‐Catalyzed Retro‐Hydroformylation of Aldehydes

open access: yesChemistryEurope
A new cobalt/organophotoredox dual catalytic system is reported for the efficient retro‐hydroformylation of aldehydes. Under the optimized conditions, a wide range of α‐monosubstituted aldehydes are readily transformed into the desired alkenes in a one ...
Augustin Nouaille   +3 more
doaj   +1 more source

Hydroformylation of Glycals [PDF]

open access: yesJournal of the American Chemical Society, 1964
Alex. Rosenthal, Derek. Abson
openaire   +1 more source

Selective conversion of syngas to C<sub>4+</sub> long-chain alcohols. [PDF]

open access: yesNat Commun
Li Y   +13 more
europepmc   +1 more source

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