Results 51 to 60 of about 6,893 (205)

Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character

Angewandte Chemie, Volume 138, Issue 32, 3 August 2026.
Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge, Emeric Schubert, Israel Fernández, Terrance J. Hadlington   +3 more
wiley   +2 more sources

Ligand Hydrogenation during Hydroformylation Catalysis Detected by In Situ High-Pressure Infra-Red Spectroscopic Analysis of a Rhodium/Phospholene-Phosphite Catalyst

Molecules
Phospholane-phosphites are known to show highly unusual selectivity towards branched aldehydes in the hydroformylation of terminal alkenes. This paper describes the synthesis of hitherto unknown unsaturated phospholene borane precursors and their ...
José A. Fuentes, Mesfin E. Janka, Aidan P. McKay, David B. Cordes, Alexandra M. Z. Slawin, Tomas Lebl, Matthew L. Clarke   +6 more
doaj   +1 more source

P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions

Molecules
Hydroformylation of olefins is widely used in the chemical industry due to its versatility and the ability to produce valuable aldehydes with 100% atom economy.
Tong Ru, Yajiao Zhang, Qiuxiang Wei, Sheng Zuo, Zhenhua Jia, Fen-Er Chen   +5 more
doaj   +1 more source

Synthesis and Characterization of Rh/B–TNTs as a Recyclable Catalyst for Hydroformylation of Olefin Containing –CN Functional Group

Nanomaterials, 2018
The TiO2-based nanotubes (TNTs, B–TNTs) of different surface acidities and their supported Rh catalysts were designed and synthesized. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission ...
Penghe Su, Xiaotong Liu, Ya Chen, Hongchi Liu, Baolin Zhu, Shoumin Zhang, Weiping Huang   +6 more
doaj   +1 more source

Gas–liquid mass transfer enhancement in the presence of nanoparticles under slug flow in microreactors

AIChE Journal, Volume 72, Issue 10, October 2026.
Abstract Nanofluids containing nanoparticles represent a promising solvent or reaction system for gas–liquid operations. Herein, the effect of nanoparticle (Al2O3 and SiO2) addition on gas–liquid slug flow pattern and mass transfer enhancement was investigated during CO2 absorption into water in microreactors.
Jie Zong, Jun Yue
wiley   +1 more source

Kinetic analysis of homogeneous catalytic reactions [PDF]

, 2012
Reaction progress kinetic analysis (RPKA) is a powerful tool for determining kinetic parameters of catalytic reactions. Many of the published articles that have used RPKA have employed reaction calorimetry for obtaining sufficient data to be reliable ...
Robb, Lynzi M.
core   +1 more source

Low-temperature hydroformylation of ethylene by phosphorous stabilized Rh sites in a one-pot synthesized Rh-(O)-P-MFI zeolite

Nature Communications, 2023
Zeolites containing Rh single sites stabilized by phosphorous were prepared through a one-pot synthesis method and are shown to have superior activity and selectivity for ethylene hydroformylation at low temperature (50 °C).
Minjie Zhao, Chengeng Li, Daviel Gómez, Francisco Gonell, Vlad Martin Diaconescu, Laura Simonelli, Miguel Lopez Haro, Jose Juan Calvino, Debora Motta Meira, Patricia Concepción, Avelino Corma   +10 more
doaj   +1 more source

Handling Experimental Data in FACPACK: Noise Effects on Duality Relations and Algorithmic Parameter Selection

Journal of Chemometrics, Volume 40, Issue 10, October 2026.
ABSTRACT The area of feasible solutions (AFS) quantifies factor ambiguity in multivariate curve resolution (MCR). Although AFS computation is well‐defined for noise‐free data, experimental datasets require constraint relaxation and parameter tuning, which influence the resulting feasible bands.
Mathias Sawall, Christoph Kubis, Alejandro Olivieri, Steven J. Roeters, Klaus Neymeyr   +4 more
wiley   +1 more source

Cationic Cobalt (II) Hydroformylation [PDF]

, 2019
While investigating a bimetallic cobalt hydroformylation catalyst a new class of monometallic cationic cobalt (II) hydroformylation catalyst were discovered.
Hood, Drew Michael, Drew Hood, null null
core   +1 more source

Pressure‐Enhanced CO2‐to‐CO Electroreduction on Ag‐Based Catalysts: Industrially Relevant Rates and Mechanistic Insights

Carbon Energy, Volume 8, Issue 10, October 2026.
Ag‐based catalysts operated under elevated CO2 pressures exhibit markedly enhanced intrinsic activity for CO formation, with OD‐Ag achieving −200 mA cm–2 and 90% FECO at −1.3 VRHE. Mechanistic analysis shows that high pressure strengthens a *COOH‐mediated pathway by increasing intermediate coverage and suppressing hydrogen evolution, establishing CO2 ...
Sheraz Ahmed, Chirong Sun, Yurim Sohn, Muhammad Shakir Hussain, Wooyul Kim, Hyung‐Suk Oh, Jaehoon Kim   +6 more
wiley   +1 more source