A multicomponent carbonylative Suzuki–Miyaura reaction was developed for the synthesis of C‐acyl glycosides. Using Pyridine‐Enhanced Precatalyst Preparation, Stabilization, and Initiation (PEPPSI‐IPr) catalysis and Mo(CO)6 as a solid CO source, the reaction enables selective carbonylation of three components in synthetically useful yields, providing a ...
Eurípedes de Aguiar +5 more
wiley +1 more source
Soil microbes in the Tibetan Plateau degrade polyvinyl chloride and harbor novel dehalogenase SerB
Polyvinyl chloride (PVC) stands as the third most widely produced synthetic polymer plastic. However, investigations into its microbial degradation significantly trail those of polyethylene (PE) and polystyrene (PS).
Yuchao Jiang +11 more
doaj +1 more source
Environmental pollution from polymers is reaching alarming levels. Nitrile‐butadiene rubber (NBR), widely used in medical glove manufacturing, contributes significantly to plastic and microplastic pollution. Nitrile gloves have become a major component of COVID‐19 pandemic‐related waste. In this study, we demonstrated the ability of haloalkalitolerant,
G. A. Syrovatskaya +4 more
wiley +1 more source
Reaction Mechanism of DL-2-Haloacid Dehalogenase from Pseudomonas sp. 113: Hydrolytic Dehalogenation Not Involving Enzyme-Substrate Ester Intermediate (MOLECULAR BIOFUNCTION-Molecular Microbial Science) [PDF]
DL-2-Haloacid dehalogenase from Pseudomonas sp. 113 (DL-DEX 113) catalyzes the hydrolytic dehalogenation of D- and L-2-haloalkanoic acids, producing the corresponding L- and D-2- hydroxyalkanoic acids, respectively.
Kurihara, Tatsuo +4 more
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Dehalogenation of Haloalkanes by Mycobacterium tuberculosis H37Rv and Other Mycobacteria [PDF]
Haloalkane dehalogenases convert haloalkanes to their corresponding alcohols by a hydrolytic mechanism. To date, various haloalkane dehalogenases have been isolated from bacteria colonizing environments that are contaminated with halogenated compounds. A
core
This review gives a summary on the representative bioinspired single‐atomic‐site catalysts (SACs) and their applications in heterogeneous electrocatalysis and photocatalysis. The fundamentals of bioinspired design strategies are systematically discussed in the context of the first shell coordination, the second/long‐range coordination, and the outer ...
Ying Wang +4 more
wiley +1 more source
Crystal Structures of Intermediates in the Dehalogenation of Haloalkanoates by L-2-Haloacid Dehalogenase [PDF]
The L-2-haloacid dehalogenase from the 1,2-dichloroethane-degrading bacterium Xanthobacter autotrophicus GJ10 catalyzes the hydrolytic dehalogenation of small L-2-haloalkanoates to their corresponding D-2-hydroxyalkanoates, with inversion of the ...
Kalk, Kor H. +8 more
core +1 more source
Pathway Dependent Isotopic Fractionation during Aerobic Biodegradation of 1,2-Dichloroethane [PDF]
1,2-Dichloroethane (1,2-DCA) is a widespread groundwater contaminant known to be biodegradable under aerobic conditions via enzymatic oxidation or hydrolytic dehalogenation reactions. Current literature reports that stable carbon isotope fractionation of
Elsner, Martin +6 more
core +1 more source
Micro and nanobubbles enhanced ozonation technology: A synergistic approach for pesticides removal
Abstract Pesticides production, consumption, and disposal around the world are raising concerns day by day for their human and environmental health impacts. Among developing treatment technologies, ozonation has attracted the attention of many researchers in recent years. It is an emerging and promising technology for removing pesticides in the aqueous
Preeti Pal, Arata Kioka
wiley +1 more source
Cellulose Acetates in Hydrothermal Carbonization: A Green Pathway to Valorize Residual Bioplastics
Pure and commercial cellulose acetates are subjected to hydrothermal carbonization as a possible end‐of‐life strategy. The plasticizers cause the material to completely dissolve in the liquid phase at 190 °C. Valuable carbonaceous solids and platform chemicals were observed in the products, proving the possibility of applying this approach in a ...
Giulia Ischia +7 more
wiley +1 more source

