Results 41 to 50 of about 36,905 (129)
A multicomponent carbonylative Suzuki–Miyaura reaction was developed for the synthesis of C‐acyl glycosides. Using Pyridine‐Enhanced Precatalyst Preparation, Stabilization, and Initiation (PEPPSI‐IPr) catalysis and Mo(CO)6 as a solid CO source, the reaction enables selective carbonylation of three components in synthetically useful yields, providing a ...
Eurípedes de Aguiar +5 more
wiley +1 more source
The Reductive Dehalogenation of Chloroethenes, Dichlorophenol, and Chlorobenzenes [PDF]
The improper disposal of chlorinated compounds has become an environmental concern and its remediation is a priority. Dehalococcoides ethenogenes strain 195 is able to reductively dehalogenate tetrachloroethene (PCE), trichloroethene (TCE) and 2,3 ...
Fung, Jennifer
core
Carboxylation, carbonylation, and dehalogenation
This chapter describes the use of N-heterocyclic carbene–metal complexes in carboxylation, carbonylation, and dehalogenation reactions.
Nelson, David
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Environmental pollution from polymers is reaching alarming levels. Nitrile‐butadiene rubber (NBR), widely used in medical glove manufacturing, contributes significantly to plastic and microplastic pollution. Nitrile gloves have become a major component of COVID‐19 pandemic‐related waste. In this study, we demonstrated the ability of haloalkalitolerant,
G. A. Syrovatskaya +4 more
wiley +1 more source
This review gives a summary on the representative bioinspired single‐atomic‐site catalysts (SACs) and their applications in heterogeneous electrocatalysis and photocatalysis. The fundamentals of bioinspired design strategies are systematically discussed in the context of the first shell coordination, the second/long‐range coordination, and the outer ...
Ying Wang +4 more
wiley +1 more source
Reaction Mechanism of DL-2-Haloacid Dehalogenase from Pseudomonas sp. 113: Hydrolytic Dehalogenation Not Involving Enzyme-Substrate Ester Intermediate (MOLECULAR BIOFUNCTION-Molecular Microbial Science) [PDF]
DL-2-Haloacid dehalogenase from Pseudomonas sp. 113 (DL-DEX 113) catalyzes the hydrolytic dehalogenation of D- and L-2-haloalkanoic acids, producing the corresponding L- and D-2- hydroxyalkanoic acids, respectively.
Kurihara, Tatsuo +4 more
core
Designing Enzymatic Reactivity with an Expanded Palette
Innovation in biocatalysis is rapidly increasingly the diversity of catalytic reactivity that can be mediated by enzymes, addressing a key bottleneck for their widespread adoption in industrial chemical synthesis. A key approach to this is building enzymes with unnatural catalytic components that provide an expanded palette with new possibilities for ...
Reuben B. Leveson‐Gower
wiley +1 more source
Microbial dehalogenation of trichloroacetic acid
A pure bacterial culture and a two-membered mixed culture were isolated that degraded trichloroacetic acid if a second, readily metabolizable substrate was present in the growth medium.
Weightman, Andrew John +2 more
core +1 more source
Purification and Characterization of Hydrolytic Haloalkane Dehalogenase from Xanthobacter autotrophicus GJ10 [PDF]
A new enzyme, haloalkane dehalogenase, was isolated from the 1,2-dichloroethane-utilizing bacterium Xanthobacter autotrophicus GJ10. The purified enzyme catalyzed the hydrolytic dehalogenation of n-halogenated C1 to C4 alkanes, including chlorinated ...
Witholt, Bernard +2 more
core +7 more sources
Micro and nanobubbles enhanced ozonation technology: A synergistic approach for pesticides removal
Abstract Pesticides production, consumption, and disposal around the world are raising concerns day by day for their human and environmental health impacts. Among developing treatment technologies, ozonation has attracted the attention of many researchers in recent years. It is an emerging and promising technology for removing pesticides in the aqueous
Preeti Pal, Arata Kioka
wiley +1 more source

