Carbon isotope fractionation during abiotic reductive dehalogenation of trichloroethene (TCE)
Dehalogenation of trichloroethene (TCE) in the aqueous phase, either on palladium catalysts with hydrogen as the reductant or on metallic iron, was associated with strong changes in delta C-13.
Bill, M. +11 more
core +3 more sources
Advances Toward Amphidinolides C, F and U: Isolations, Synthetic Studies and Total Syntheses
Amphidinolides C, F and U are a sub‐class of polyketides sharing a similar structure, isolated from dinoflagellates or octocoral sponges and exhibiting high cytotoxic activity. This review discloses the progress made in their isolations and structural determinations and the various synthetic approaches and successful attempts leading to their total ...
Ismaila Ciss +3 more
wiley +1 more source
Meta‐omics assisted microbial gene and strain resources mining in contaminant environment
Abstract Human activities have led to the release of various environmental pollutants, triggering ecological challenges. In situ, microbial communities in these contaminated environments are usually assumed to possess the potential capacity of pollutant degradation.
Yiqun Huang +5 more
wiley +1 more source
Pure Water-Induced Dehalogenation of 2,4-Di-tert-amino-6-substituted-5-halogenopyrimidines
Dehalogenation of 5-halogenopyrimidine derivatives in boiling pure water was accomplished in high yields. The substrate and pure water are the only two reaction components in this process.
Mahsa Mousavi (5019053) +3 more
core +1 more source
Evolutionary obstacles and not C–F bond strength make PFAS persistent
C–F bonds can be cleaved by microbes. However, evolution must overcome many obstacles to biodegrade PFAS. Abstract The fate of organic matter in the environment, including anthropogenic chemicals, is largely predicated on the enzymatic capabilities of microorganisms.
Lawrence P. Wackett
wiley +1 more source
The 21-dehydroxglation of corticosteroids of Eubacterium lentum and the dehalogenation of 4-chlorobenzoic acid by 4-chlorobenzoate dehalogenase [PDF]
Two enzyme mechanisms were investigated: the 21-dehydroxylation of corticosteroids by Eubacterium lentum and the dehalogenation of 4-chlorobenzoic acid by Pseudomonas sp. CBS 3.
Ninniss, Ronald William.
core +1 more source
Mechanisms of bacterially catalyzed reductive dehalogenation
Nine bacteria were tested for the ability to dehalogenate tetrachloromethane (CT), tetrachloroethene (PCE), and 1, 1, 1-trichloroethane (TCA) under anaerobic conditions. Three bacteria were able to reductively dehalogenate CT.
Picardal, Flynn William
core +3 more sources
2.6 Carboxylation, Carbonylation, and Dehalogenation
This chapter describes the use of N-heterocyclic carbene–metal complexes in carboxylation, carbonylation, and dehalogenation reactions. Catalysts based on copper, gold, palladium, rhodium, and nickel are considered.
D. Nelson
core +1 more source
Haloalkane hydrolysis by Rhodococcus erythropolis cells: Comparison of conventional aqueous phase dehalogenation and nonconventional gas phase dehalogenation [PDF]
Biofiltration of air polluted by volatile organic compounds is now recognized by the industrial and research communities as an effective and viable alternative to standard environmental technologies.
Erable, Benjamin +4 more
core +1 more source
D-2-haloacid dehalogenases (D-DEXs) catalyse the hydrolytic dehalogenation of D-2-haloacids, releasing halide ions and producing the corresponding 2-hydroxyacids.
Yayue Wang +4 more
core +1 more source

