Cellulose Acetates in Hydrothermal Carbonization: A Green Pathway to Valorize Residual Bioplastics
Pure and commercial cellulose acetates are subjected to hydrothermal carbonization as a possible end‐of‐life strategy. The plasticizers cause the material to completely dissolve in the liquid phase at 190 °C. Valuable carbonaceous solids and platform chemicals were observed in the products, proving the possibility of applying this approach in a ...
Giulia Ischia +7 more
wiley +1 more source
Discovering new arene-catalyzed lithiations [PDF]
La litiació catalitzada per hidrocarburs aromàtics és una metodologia útil i versàtil que promou els processos de litiació en condicions de reacció molt suaus.
Yus, Miguel
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The structure of the hexameric atrazine chlorohydrolase AtzA
Atrazine chlorohydrolase (AtzA) was discovered and purified in the early 1990s from soil that had been exposed to the widely used herbicide atrazine. It was subsequently found that this enzyme catalyzes the first and necessary step in the breakdown of ...
Balotra, S. +5 more
core +1 more source
A novel method is presented, demonstrating the facile generation of α‐acyloxy carboxamide radicals via photoredox catalysis of Passerini adducts, obtained employing a 4‐formyl‐1,4‐dihydropyridine. These radicals efficiently undergo Giese reactions with various olefins, yielding novel Passerini compounds unattainable through traditional aldehyde‐based ...
Francesca Brunelli +5 more
wiley +1 more source
Total syntheses of conformationally-locked difluorinated pentopyranose analogues and a pentopyranosyl phosphate mimetic [PDF]
Trifluoroethanol has been elaborated, via a telescoped sequence involving a metalated difluoroenol, a difluoroallylic alcohol, [2,3]-Wittig rearrangement, and ultimately an RCM reaction and requiring minimal intermediate purification, to a number of ...
Miles, Jonathan A. L. +4 more
core +1 more source
Advances Toward Amphidinolides C, F and U: Isolations, Synthetic Studies and Total Syntheses
Amphidinolides C, F and U are a sub‐class of polyketides sharing a similar structure, isolated from dinoflagellates or octocoral sponges and exhibiting high cytotoxic activity. This review discloses the progress made in their isolations and structural determinations and the various synthetic approaches and successful attempts leading to their total ...
Ismaila Ciss +3 more
wiley +1 more source
Meta‐omics assisted microbial gene and strain resources mining in contaminant environment
Abstract Human activities have led to the release of various environmental pollutants, triggering ecological challenges. In situ, microbial communities in these contaminated environments are usually assumed to possess the potential capacity of pollutant degradation.
Yiqun Huang +5 more
wiley +1 more source
Role of Dehalogenases in Aerobic Bacterial Degradation of Chlorinated Aromatic Compounds [PDF]
This review was conducted to provide an overview of dehalogenases involved in aerobic biodegradation of chlorinated aromatic compounds. Additionally, biochemical and molecular characterization of hydrolytic, reductive, and oxygenolytic dehalogenases was ...
Hanhong Bae, Pankaj Kumar Arora
core +2 more sources
Toxicity of Dietary Exposure to 3‐Monochloropropanediol, Glycidol, and Their Fatty Acid Esters
3‐Monochloropropane‐1,2‐diol (3‐MCPD), 2,3‐epoxy‐1‐propanol (glycidol), and their fatty acid esters are heat‐induced food toxicants that have widely been investigated. This review study presents an overview of current knowledge about the dietary toxicity of 3‐MCPD, glycidol, and their fatty acid esters. A literature search in two databases from January
Daniel Sitsofe Yabani +4 more
wiley +1 more source
The application of nitrido manganese reagents to the synthesis of protected N-methyl D-fucosamine [PDF]
A synthesis of protected D-fucosamine and N-methyl fucosamine from D-galactose is described. The synthesis is carried out in ten steps and includes the amination reaction of D-fucal with an easily prepared Mn≡N ...
Carreira, Erick M. +3 more
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