Results 171 to 180 of about 111,305 (353)

Identification of Key Active-Site Positions Controlling the Chemoselectivity of Aspergillus Brasiliensis Unspecific Peroxygenase. [PDF]

open access: yesChembiochem
Schmitz F   +8 more
europepmc   +1 more source

Acetylation‐Deacetylation‐Driven Natural Product Biosynthesis

open access: yesChemistryEurope, EarlyView.
This review summarizes the role of acetylation‐deacetylation in natural product biosynthesis, including acetylation followed by deacetylation after several biosynthetic steps, acetylation‐mediated rearrangement, acetylation‐triggered elimination, and the acetylation cycle as a regulatory mechanism. These processes are vital for the formation of complex
Huibin Wang, Ikuro Abe
wiley   +1 more source

Biosynthesis of reveromycin derivatives by altering the regioselectivity of cytochrome P450revI. [PDF]

open access: yesChem Sci
Yong YF   +9 more
europepmc   +1 more source

Identification of Pyrrolizilactone Biosynthetic Gene Cluster with Unique Short‐Chain Dehydrogenase Gene for 3‐Methylproline Formation

open access: yesChemistryEurope, EarlyView.
A standalone enzyme, derived from the reductase domain of a polyketide synthase‐nonribosomal peptide synthetase hybrid enzyme, is identified as a pyrroline carboxylate reductase. This enzyme is involved in the biosynthesis of 3‐methylproline, an amino acid building block of a unique tricyclic pyrrolizidinone structure of a fungal metabolite ...
Naoki Kato   +6 more
wiley   +1 more source

16α HYDROXYLATION OF DEHYDROEPIANDROSTERONE BY HUMAN FETAL TISSUES

open access: bronze, 1967
Tetsuya Nakayama   +5 more
openalex   +2 more sources

Three distinct strategies lead to programmable aliphatic C-H oxidation in bicyclomycin biosynthesis. [PDF]

open access: yesNat Commun
Wu L   +8 more
europepmc   +1 more source

Catalytic Oxidation of Naphthalene and Polycyclic Arenes by Iron(III) TAML/H2O2 in Water Aiming at Their Efficient Removal from Aqua Natural Systems

open access: yesChemistry – A European Journal, EarlyView.
Fe‐TAML in the presence of hydrogen peroxide efficiently catalyzes the oxidative degradation of naphthalene in aqueous medium of neutral pH. Products are identified and key mechanistic features are discussed. Abstract The electron transfer from naphthalene at an oxidized iron TAML species (TAML = tetraamido macrocyclic ligand) is a key step of its ...
Parameswar Pal   +3 more
wiley   +1 more source

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