Results 201 to 210 of about 194,006 (386)

Rubrolides A, D, P, T, U: Total Syntheses and Antibacterial Evaluation of Highly Brominated Marine Natural Products

open access: yesChemistryEurope, EarlyView.
Following the Danube Flow. The first total syntheses of highly brominated rubrolides T, U, and U‐analog, together with the efficient and divergent syntheses of rubrolides A, D, and P. The dibrominated key intermediate, obtained via a Suzuki‐Miyaura cross‐coupling reaction, is the centerpiece of the synthesis.
Jasmin Janneschütz   +7 more
wiley   +1 more source

A Review on Applications and Challenges of Fullerenes in Proton Exchange Membranes

open access: yesCarbon Energy, EarlyView.
This review is devoted to the analysis of the use of fullerenes and their functionalized derivatives to improve the efficiency of proton exchange membranes. The synthetic methods, structure, properties, and proton transfer mechanisms of fullerene‐containing membranes are discussed in detail. Promising areas of scientific research are discussed, and key
Ruslan Usmanov, Alexander Pozdnyakov
wiley   +1 more source

Pyrrolic‐Nitrogen‐Enriched Aerogels With Magnetic Responsiveness Enable Cooperative Hydrogen‐Bond Regulation for High‐Performance Solar Interfacial Evaporation

open access: yesCarbon Energy, EarlyView.
A pyrrolic‐nitrogen‐enriched ferromagnetic aerogel enables sophisticated cooperative regulation of hydrogen bonding, whereby this dual‐regulatory mechanism effectively reduces vaporization enthalpy while simultaneously enhancing molecular dynamics. The system demonstrates exceptional self‐cleaning capability and exhibits superior performance in the ...
Dongxue Wang   +8 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

open access: yesChemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez   +3 more
wiley   +1 more source

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