Results 131 to 140 of about 55,611 (282)
Citation: 'ammonium imines' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.A00291 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire +1 more source
Titanium-mediated reductive cross-coupling reactions of imines with terminal alkynes: An efficient route for the synthesis of stereodefined allylic amines [PDF]
Kebin Mao +5 more
openalex +1 more source
Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley +2 more sources
Total Synthesis of the Spirocyclic Bis‐Indole Alkaloid (−)‐Owerreine via a [4+2] Annulation
The total synthesis of the bis‐indole alkaloid (−)‐owerreine has been accomplished by a diastereoselective [4+2] annulation between an enamine and an α,β−unsaturated indolenine precursor to form the 3‐spirocyclic tetrahydropyridine linkage of the natural product. DFT calculations allow an understanding of the mechanism of the key annulation.
Elisa Coll +4 more
wiley +2 more sources
The excited‐state intramolecular proton transfer (ESIPT) photoswitch tpmSA, which features an oxygen−acceptor, exhibits higher photochromic contrast (ΔE*Lab>74) than its nitrogen‐acceptor Schiff base analogues (ΔE*Lab<30). Theoretical calculations indicate that tpmSA effectively suppresses GSIPT, thereby enhancing the contrast.
Yahui Chen +10 more
wiley +2 more sources
The thiocarbenium ion rearrangement of 3‐dihydrodisorhabdin B greatly increases the recovery of aleutianamine from Latrunculia spp., a pyrroloiminoquinone natural product with potent activity against drug‐resistant cancers, collected from the deep‐ocean along the Aleutian Islands.
Cody F. Dickinson +13 more
wiley +2 more sources

