Results 21 to 30 of about 55,611 (282)

Synthesis of Aminopropyltriethoxysilyl-Substituted Imines and Amides

open access: yesMolbank, 2021
A series of small molecules containing aminopropyltriethoxysilyl-substituted imines and amides were synthesized so that they could potentially be incorporated into self-assembled monolayers (SAMs) on metal oxide surfaces.
Surya R. Banks   +2 more
doaj   +1 more source

A Study of the Interaction of a New Benzimidazole Schiff Base with Synthetic and Simulated Membrane Models of Bacterial and Mammalian Membranes

open access: yesMembranes, 2021
Biological membranes are complex dynamic systems composed of a great variety of carbohydrates, lipids, and proteins, which together play a pivotal role in the protection of organisms and through which the interchange of different substances is regulated ...
Alberto Aragón-Muriel   +4 more
doaj   +1 more source

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines

open access: yesMolecules, 2016
Novel silylium ions with N-heterocyclic imines were successfully synthesized. The reaction of trimethylsilyl imidazolin-2-imine Me3SiNIPr (NIPr = bis(2,6-diisopropylphenyl)-imidazolin-2-imino) with B(C6F5)3 leads to dimeric imino-substituted silylium ...
Tatsumi Ochiai   +2 more
doaj   +1 more source

Differentiation between Enamines and Tautomerizable Imines Oxidation Reaction Mechanism using Electron-Vibration-Vibration Two Dimensional Infrared Spectroscopy

open access: yesMolecules, 2019
Intermediates lie at the center of chemical reaction mechanisms. However, detecting intermediates in an organic reaction and understanding its role in reaction mechanisms remains a big challenge.
Fengqin Long   +4 more
doaj   +1 more source

Dendrimers Functionalized with Palladium Complexes of N-, N,N-, and N,N,N-Ligands

open access: yesMolecules, 2021
Pyridine, pyridine imine, and bipyridine imine ligands functionalized by a phenol have been synthesized and characterized, in many cases by X-ray diffraction.
Quentin Vanbellingen   +5 more
doaj   +1 more source

Hexacoordinate Silicon Compounds with a Dianionic Tetradentate (N,N′,N′,N)-Chelating Ligand

open access: yesInorganics, 2016
In the context of our systematic investigations of penta- and hexacoordinate silicon compounds, which included dianionic tri- (O,N,O′; O,N,N′) and tetradentate (O,N,N,O; O,N,N′,O′) chelators, we have now explored silicon coordination chemistry with a ...
Daniela Gerlach   +2 more
doaj   +1 more source

Imine reductases (IREDs)

open access: yesCurrent Opinion in Chemical Biology, 2017
Imine reductases (IREDs) have emerged as a valuable new set of biocatalysts for the asymmetric synthesis of optically active amines. The development of bioinformatics tools and searchable databases has led to the identification of a diverse range of new IRED biocatalysts that have been characterised and employed in different synthetic processes.
Mangas-Sanchez, Juan   +8 more
openaire   +5 more sources

On the mechanism of imine elimination from Fischer tungsten carbene complexes

open access: yesBeilstein Journal of Organic Chemistry, 2016
(Aminoferrocenyl)(ferrocenyl)carbene(pentacarbonyl)tungsten(0) (CO)5W=C(NHFc)Fc (W(CO)5(E-2)) is synthesized by nucleophilic substitution of the ethoxy group of (CO)5W=C(OEt)Fc (M(CO)5(1Et)) by ferrocenyl amide Fc-NH– (Fc = ferrocenyl).
Philipp Veit   +2 more
doaj   +1 more source

N-(4-Chlorophenyl)-9H-fluoren-9-imine

open access: yesIUCrData, 2019
The title compound, C19H12ClN, was synthesized via reaction of 9-fluorenone and 4-chloroaniline using p-toluenesulfonic acid in toluene. The dihedral angle between the fluorene moiety (r.m.s.
Guy Crundwell   +3 more
doaj   +1 more source

New pyrene and fluorene-based π-conjugated Schiff bases: Theoretical and experimental investigation of optical properties [PDF]

open access: yesJournal of the Serbian Chemical Society
The new Schiff bases with D-π-A system were synthesized by the reaction of polycyclic aldehydes and substituted benzothiazoles. The structures of the synthesized Schiff bases (7a and 9a) were determined by FT-IR, 1H- -NMR, 13C-NMR, ESI-Mass and elemental
Sivrikaya Yunuscan   +4 more
doaj   +1 more source

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