Results 71 to 80 of about 64,220 (327)
Raman Spectroscopy Reveals Phase Separation in Imine-Based Covalent Adaptable Networks [PDF]
, 2022 Sybren K. Schoustra +5 more
openalex +1 more source
Covalent Organic Frameworks for Water Sorption: The Importance of Framework Physical Stability
Advanced Functional Materials, EarlyView.This study explores the water‐vapor stability of 2D covalent organic frameworks (COFs) with varying pore sizes. Results reveal microporous COFs demonstrate superior stability compared to mesoporous ones, despite lower water uptake. Mesoporous keto‐enamine‐linked COFs show enhanced stability due to intralayer hydrogen bonds, confirmed by simulations and
Wei Zhao +13 more
wiley +1 more source
Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] Pathways [PDF]
, 2011 In this paper we describe the phosphine-catalyzed [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] annulations of azomethine imines and allenoates. These processes mark the first use of azomethine imines in nucleophilic phosphine catalysis, producing ...
Benitez, Diego +12 more
core +2 more sources
Manganese carbonyl-mediated reactions of azabutadienes with phenylacetylene, methyl acrylate and other unsaturated molecules [PDF]
, 2004 Reaction of PhCH₂Mn(CO)₅ with l,4-di-aryl-1-aza-1,3-butadienes gave substituted pyrrolinonyl rings which were η⁴-coordinated to a Mn(CO)₃ group. These are formed by intramolecular CO insertion into a (non-isolated) cyclomanganated intermediate, followed ...
Mace, Wade +3 more
core +2 more sources
Tailoring the Properties of Functional Materials With N‐Oxides
Advanced Functional Materials, EarlyView.The properties of materials bearing N‐oxide groups are often dominated by the polar N+─O− bond. It provides hydrophilicity, selective ion‐binding, electric conductivity, or antifouling properties. Many of the underlying mechanisms have only recently been discovered, and the interest in N‐oxide materials is rapidly growing.
Timo Friedrich +5 more
wiley +1 more source
On the Additions of Lithium Methyl p-Tolyl Sulfoxide to N-(PMP)Arylaldimines
Molecules, 2001 The results presented in this paper confirm that the stereochemical outcome of the reversible additions of lithium (R)-methyl p-tolyl sulfoxide to N-arylidene-p-anisidines (NPMP imines) depends on: (a) the reaction conditions used and (b) the electronic ...
Matteo Zanda +5 more
doaj +1 more source
1,3-Dipolar cycloadditions of azomethine imines [PDF]
, 2015 Azomethine imines are considered 1,3-dipoles of the aza-allyl type which are transient intermediates and should be generated in situ but can also be stable and isolable compounds.
Nájera, Carmen +2 more
core +3 more sources
Advanced Functional Materials, EarlyView.Fe─NC porous oxygen reduction electrocatalysts are prepared employing a 2,4,6‐Triaminopyrimidine‐based porous organic polymer, a Mg2+ Lewis acid, and a low‐temperature cation exchange protocol. Using the polymer precursor achieves high pyrolysis yields and results in atomically dispersed FeNx sites. The resulting catalysts feature hierarchical porosity
Eliot Petitdemange +11 more
wiley +1 more source
Nature CommunicationsC–C and C–X bond forming reactions are essential tools in organic synthesis, constantly revolutionizing human life. Among the key methods for constructing new chemical bonds are nucleophilic addition reactions involving imines.
Wei Wang +9 more
doaj +1 more source
β-Formyl- and β-Vinylporphyrins: Magic Building Blocks for Novel Porphyrin Derivatives
Molecules, 2017 Porphyrins bearing formyl or vinyl groups have been explored as starting materials to prepare new compounds with adequate features for different applications.
Ana F. R. Cerqueira +6 more
doaj +1 more source