Results 31 to 40 of about 90,075 (209)

Direct Oxidative C-P Bond Formation of Indoles with Dialkyl Phosphites

open access: yes, 2012
The direct phosphonation of indoles was developed. In this reaction, dialkyl phosphites and indoles were used as substrates, and the C-P bond was formed through oxidative coupling mediated by silver(I) acetate.
Wu, Fan   +4 more
core   +1 more source

Predictive and prognostic biomarkers of Bacillus Calmette‐Guérin therapy failure in bladder cancer patients: A systematic review

open access: yesMolecular Oncology, EarlyView.
High‐risk bladder cancer is typically treated with Bacillus Calmette‐Guérin (BCG), but 30–40% of patients relapse. No FDA‐ or CE‐approved biomarkers currently predict or prognosticate BCG failure. We systematically reviewed the literature and identified 72 eligible studies, revealing several promising biomarkers associated with BCG treatment response ...
Rui Ribeiro‐Pereira   +7 more
wiley   +1 more source

Edible Cuttlefish Ink: Complex Chemistry, Structure, and Electrical Response

open access: yesAdvanced Engineering Materials, EarlyView.
An integrated approach of chemistry‐structure‐electrical properties is used to assess the potential of edible cuttlefish ink as a bio‐based conductive ink for printable electronics. Chromatography and Neutron Activation Analysis reveal a fascinating molecular and elemental diversity.
Camille Bour‐Cardinal   +5 more
wiley   +1 more source

An Overlooked Transport Mechanism in Organic Mixed Conductors

open access: yesAdvanced Functional Materials, EarlyView.
Electrical transport in organic mixed ionic‐electronic conductors is commonly described by ionic and electronic conduction. Here, eumelanin reveals that polarization‐assisted displacement currents constitute an additional transport component that coexists with conductive transport.
Natan L. Nozella   +5 more
wiley   +1 more source

Total Synthesis of Tambromycin Enabled by Indole C–H Functionalization [PDF]

open access: yesOrganic Letters, 2018
The total synthesis of tambromycin (1), a recently isolated tetrapeptide, is reported. This unusual natural product possesses a highly modified tryptophan-derived indole fragment fused to an α-methylserine-derived oxazoline ring, and a unique noncanonical amino acid residue named tambroline (11).
Galen P. Miley   +4 more
openaire   +2 more sources

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

open access: yesAdvanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen   +7 more
wiley   +1 more source

Síntese ambientalmente adequada de 3-selenil-indóis [PDF]

open access: yes, 2014
(Dissertação (mestrado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2014No presente trabalho desenvolveu-se uma nova metodologia sintética ambientalmente ...
Ferreira, Natasha Londero
core  

Palladium-Catalyzed Cyclization/Carboalkoxylation of Alkenyl Indoles

open access: yes, 2016
Reaction of 1-methyl-2-(4-pentenyl)indole with a catalytic amount of PdCl2(CH3CN)2 (5 mol %) and a stoichiometric amount of CuCl2 (3 equiv) in methanol under CO (1 atm) at room temperature for 30 min led to cyclization/carboalkoxylation to form the ...
Ross A. Widenhoefer (1375383)   +1 more
core   +1 more source

Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation

open access: yesAdvanced Optical Materials, EarlyView.
A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu   +10 more
wiley   +1 more source

Underground Signals: The Ecological Power of Root Volatiles

open access: yesAdvanced Science, EarlyView.
Root volatiles mediate rhizosphere chemical communication, shaping interactions among plants, microbes, herbivores, and natural enemies. Their production, transport, and perception underpin ecological adaptation, multitrophic interactions, and plant resilience, offering opportunities for sustainable crop protection, resilient agroecosystems, and ...
Xueyao Cao   +31 more
wiley   +1 more source

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