Results 61 to 70 of about 13,233 (208)

Light‐Programmable Interfaces: From Molecular Photoswitching to Adaptive Membrane Separations

Advanced Materials Interfaces, EarlyView.
This review advances an interface‐centered framework for light‐responsive membranes, linking molecular photoswitches (azobenzene (AZO), spiropyran (SP), diarylethene (DAE), donor–acceptor Stenhouse adducts (DASA), photoacid) to integration strategies in polymeric, porous, self‐assembled, and mixed‐matrix systems.
Liangliang Zhang, Senlin Gu, Jianyang Zhao, Xiaojuan Hao, Lu Hua Li, Jihua Li, Lingxue Kong   +6 more
wiley   +1 more source

Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer

Angewandte Chemie, Volume 138, Issue 13, 23 March 2026.
Energy transfer is the key to the successful photocyclization of the title compounds to 3,4‐disubstituted 2‐azetidinones. If the substituent at the nitrogen atom is primary (R2 = H), trans products are formed exclusively. The triplet state of xanthen‐9‐one (XT) was found to be quenched by an allene amide (R, R2 = H, R1 = Bn, and R3 = Ph) with a ...
Johannes Hofer, Maria‐Sophie Bertrams, Christoph Kerzig, Thorsten Bach   +3 more
wiley   +2 more sources

Crystal structure of 1′-(prop-2-yn-1-yl)-1,4-dihydrospiro[benzo[d][1,3]oxazine-2,3′-indolin]-2′-one

Acta Crystallographica Section E: Crystallographic Communications, 2015
In the title compound, C18H14N2O2, the six-membered oxazine ring adopts a half-chair conformation and its mean plane makes a dihedral angle of 83.23 (7)° with the pyrrolidine ring of the indoline ring system. In the crystal, molecules are linked via N—H..
Y. AaminaNaaz, J. Kamalraja, G. Vimala, P. T. Perumal, A. SubbiahPandi   +4 more
doaj   +1 more source

Novel synthesis and characterisation of 3,3-dimethyl-50-(2-benzothiazolyl)- spironaphth(indoline-2,30-[3H]naphth[2,1-b] [1,4]oxazine) derivatives [PDF]

, 2009
Novel modified spirooxazines (SOs) with additional chelating groups were synthesised and the crystal structure of one of these was determined. UV–vis spectroscopic characterization of the photoisomerization of the SO derivatives shows that the ...
Alhashimy, Atabekyan, Baillet, Benkovic, Bertelson, Boeyens, Byrne, Byrne, Cao, Chamonttin, Chu, Clegg, Collins, Crano, Deligeorgiev, Dermot Diamond, Desvergne, Favaro, Feringa, Gőrner, Hirschberg, Irie, Jeliazkova, Kawata, Ko, Le Baccon, Lehn, Lokshin, Löhr, Maeda, Miler-Srenger, Millini, Minkin, Minkovska, Nameer Alhashimy, Nishikiori, Phillips, Pimienta, Pina, Preigh, Radu, Robert Byrne, Rosario, Scarmagnani, Schaffner, Stela Minkovska, Tamai, Tamaki, Taylor, Tian, Uznanski, Wojtyk, Zhou   +52 more
core   +1 more source

Asymmetric Synthesis of Spirooxindoles via Nucleophilic Epoxidation Promoted by Bifunctional Organocatalysts [PDF]

, 2018
Taking into account the postulated reaction mechanism for the organocatalytic epoxidation of electron-poor olefins developed by our laboratory, we have investigated the key factors able to positively influence the H-bond network installed inside the ...
Abbate, Sergio, Gasperi, Tecla, Longhi, Giovanna, Lupattelli, Paolo, Mazzeo, Giuseppe, Mazziotta, Andrea, Miceli, Martina, Palumbo, Chiara, Roma, Elia, Tosi, Eleonora   +9 more
core   +2 more sources

Research on synthesis of microwave‐assisted heterocyclic compounds with eco‐friendly solvents and transition metals via C–H activation

Bulletin of the Korean Chemical Society, EarlyView.
This review summarizes microwave‐assisted transition‐metal catalysis for constructing N‐ and O‐heterocycles, highlighting rapid C–H and pre‐activated C–X activation, improved selectivity, and green synthetic efficiency. Abstract Microwave‐assisted organic synthesis provides a rapid and sustainable platform for synthesizing various heterocycles ...
Woo‐Jin Park, Ye Ri Han, Hyejeong Lee
wiley   +1 more source

Catalytic dehydrogenative Si-N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base [PDF]

, 2013
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence
Aiguabella, Nuria, Klare, Hendrik F. T., Königs, C. David F., Müller, Maria F., Oestreich, Martin   +4 more
core   +1 more source

Precision Catalysis in Dehydrogenation of Liquid Organic Hydrogen Carriers: Molecular Structure‐Geometry‐Electronic Interplay for Enhanced Hydrogen Evolution

Carbon Energy, EarlyView.
Atomic‐scale design principles for LOHC dehydrogenation: Tailoring geometric and electronic effects in metal catalysts to bridge the molecular structure of LOHC and dehydrogenation performance. ABSTRACT The advancement of hydrogen‐based energy systems necessitates innovative solutions for safe, efficient hydrogen storage and transportation.
Yongxiao Tuo, Jingying Qu, Huailu Sun, Hongwei Gai, Xiangyuan Qu, Junlun Zhu, Xiaohui Sun, De Chen, Xiang Feng   +8 more
wiley   +1 more source

Spiro[pyrrolidine-3,3′-oxindoles] and Their Indoline Analogues as New 5-HT6 Receptor Chemotypes

Molecules, 2017
Synthetic derivatives of spiro[pyrrolidinyl-3,3′-oxindole] alkaloids (coerulescine analogues) were investigated as new ligands for aminergic G-protein coupled receptors (GPCRs).
Ádám A. Kelemen, Grzegorz Satala, Andrzej J. Bojarski, György M. Keserű   +3 more
doaj   +1 more source

Gas Phase dynamics of spiropyrans and spirooxazines molecules [PDF]

, 2006
The gas-phase dynamics of two classes of photochromic molecules, three spiropyrans and one spirooxazine, have been investigated here using both time-resolved mass spectrometry and photoelectron spectroscopy approaches.
Buntin, Guy, D. Raffael, Kevin, Mestdagh, Jean-Michel, Poisson, L., Soep, Benoît   +4 more
core   +3 more sources