Results 41 to 50 of about 451 (130)
In the title dispiro compound, C32H26ClN3O2, the cyclohexanone ring of the isoquinoline unit has a distorted envelope conformation, with the methylene C atom adjacent to the spiro C atom as the flap.
R. Vishnupriya +5 more
doaj +1 more source
A New Indoline Rearrangement [PDF]
The keto pyrrolidone 2 in the presence of acid produces the enamine 3a and the rearranged quinolone 4. Evidence is presented for the mechanism of this new rearrangement, the key step being a remarkably facile opening and reclosure of the indoline ring [Formula: see text] which even occurs in acetic acid.
Vinod Dave +2 more
openaire +1 more source
Unlocking Stereodefined Olefins by Z‐Selective Transition Metals‐catalyzed C−H Activations
The synthesis of Z‐olefins is an important challenge in synthetic organic chemistry. Within this review, we report a comprehensive overview of transition metals‐catalyzed Z‐selective C–H activations of (hetero)arenes for the synthesis of stereodefined olefins.
Francesco Capranica +2 more
wiley +1 more source
Synthesis and antimicrobial evaluation of spiro compound containing 1,2,4-triazole and isatin
The synthesis of 6'-Phenyl-4'-thioxo-3'-(4H-1,2,4-triazole-4-yl)-3',4'-dihydrospiro [Indoline-3,2'-[1,3,5]oxadiazine]-2-one (5a-h) is carried out by two a step reaction, beginning with acid catalyzed condensation of 4H-1,2,4-triazole-4-amine (1)
Visha P. Modi +2 more
doaj +1 more source
A new family of pentamethylcyclopentadienyl (C5Me5, Cp*) iridium(III), rhodium(III), and ruthenium(III) complexes bearing bidentate 1,2‐dioxime ligands was developed and their catalytic performances were evaluated in the hydrogen‐borrowing‐type H/D exchange of amines using D2O as both solvent and deuterium source. Iridium derivatives achieved excellent
Francesco Taglieri +8 more
wiley +1 more source
2′-Amino-5′-benzoyl-5-bromo-6′-methyl-2-oxospiro[indoline-3,4′-pyran]-3′-carbonitrile
In the title compound, C21H14BrN3O3, the indoline ring system is almost planar, while the pyran ring is in flattened-boat conformation. In the crystal, N—H...O and N—H...N hydrogen bonds link the molecules, enclosing R22(8) and R22(12) ring motifs, into (
Farid N. Naghiyev +4 more
doaj +1 more source
Mechanochemistry as an Emerging Tool for Organofluorine Chemistry
Fluorinated scaffolds are central across many areas of chemistry, driving the demand for efficient and sustainable synthetic methods. Mechanochemistry has emerged as a powerful alternative to conventional approaches, offering reduced environmental impact, shorter reaction times, and unique reactivity and selectivity.
Marie Caldiero +3 more
wiley +1 more source
5-Bromo-1-nonylindoline-2,3-dione
In the title compound, C17H22BrNO2, the indoline ring system, the two ketone O atoms and the Br atom are nearly coplanar, with an r.m.s. deviation of 0.029 Å.
Yassine Kharbach +4 more
doaj +1 more source
ABSTRACT A novel series of 5‐chloro‐N‐alkyl‐1′,1″‐dimethyl‐4′‐aryldispiro[indene‐2,3′‐pyrrolidine‐2′,3″‐indoline]−1,2″(3H)‐diones (4a–r) was rationally designed and synthesized via a one‐pot multicomponent reaction of N‐alkylated 5‐chloroisatin derivatives, 2‐(arylmethylidene)−2,3‐dihydro‐1H‐inden‐1‐ones (2a–i), and sarcosine (3).
Aisha A. Alsfouk +7 more
wiley +1 more source
The crystal structures of the title compounds, C19H19NO and C31H34N2O, were determined as part of an experiment in an undergraduate teaching laboratory that demonstrates the relationship between molecular structure and function.
Joseph O. S. Beckett +5 more
doaj +1 more source

