Results 41 to 50 of about 33,147 (342)

Modificação do acetato de celulose em meio homogêneo via reações de condensação com diferentes isocianatos Homogeneous chemical modification of cellulose acetate using different isocyanates

open access: yesPolímeros, 1998
Este estudo descreve uma série de reações envolvendo os grupos isocianatos (NCO) e os grupos hidroxílicos do acetato de celulose com grau de substituição (DS) igual a 2,4.
Vagner R. Botaro, Alessandro Gandini
doaj   +1 more source

Novel Functional Materials via 3D Printing by Vat Photopolymerization

open access: yesAdvanced Functional Materials, EarlyView.
This Perspective systematically analyzes strategies for incorporating functionalities into 3D‐printed materials via Vat Photopolymerization (VP). It explores the spectrum of achievable functionalities in recently reported novel materials—such as conductive, energy‐storing, biodegradable, stimuli‐responsive, self‐healing, shape‐memory, biomaterials, and
Sergey S. Nechausov   +3 more
wiley   +1 more source

Iron(II) catalyzed hydrophosphination of isocyanates [PDF]

open access: yes, 2017
The first transition metal catalyzed hydrophosphination of isocyanates is presented. The use of low-coordinate iron(II) precatalysts leads to an unprecedented catalytic double insertion of isocyanates into the P-H bond of diphenylphosphine to yield ...
Blake, Alexander J.   +4 more
core   +3 more sources

4D‐Printable Poly(Thio)urethane Photoresins With Reactive Oxygen Species Responsiveness and Anti‐Inflammatory Functionality

open access: yesAdvanced Functional Materials, EarlyView.
This work introduces UV‐curable poly(thio)urethane (PSU) thermosets as 4D printable scaffolds responsive to oxidative stress. PSU networks with 100 wt.% polypropylene glycol (PPG) effectively suppress inflammatory markers in microglial cells to basal values.
Xabier Lopez de Pariza   +10 more
wiley   +1 more source

The wheat straw lignin as renewable polyol for polyurethanes elastomers [PDF]

open access: yes, 2012
The novel wheat straw) produced on CIMV pilot plant (France) was sequential extracted with organic solvents of different polarity (dichloromethane, methanol and dichloromethane/methanol mixture.
Arshanitsa, Alexandr   +3 more
core  

Synthesis of N-Z, N′-Formyl α-Amino Acid Derived Gem-Diamines [PDF]

open access: yes, 2008
A variety of N-carbobenzoxy, N′-formyl gem-diaminoalkyl derivatives have been obtained through Goldsmith-Wick reaction of Z-α-amino acid/peptide acid derived isocyanates with 96% HCOOH in presence of 4-dimethylaminopyridine (DMAP) as catalyst.
Narendra, N., Sureshbabu, V.V.
core   +2 more sources

Biological Monitoring for Isocyanates [PDF]

open access: yesThe Annals of Occupational Hygiene, 2007
Isocyanates are reactive chemicals and thousands of workers may be exposed to them during their manufacture and use in a wide range of products. They are classed as sensitizers and are a major cause of occupational asthma in the UK. Workplace exposure limits are low and control of exposure often depends on personal respiratory protection.
openaire   +2 more sources

A New Series of Bis (Thiosemicarbazone) Derivatives: Synthesis, Spectroscopic Characterization, and Antioxidant Activities

open access: yesSakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi
New bis (thiosemicarbazone) derivatives (1-5) were obtained from thiophene-2,5-dicarbaldehyde and numerous thiosemicarbazides. The thiosemicarbazides were prepared various isothiocyanates and hydrazine monohydrate.
Halit Muğlu, Hasan Yakan
doaj   +1 more source

The preparation of new functionalized [2.2]paracyclophane derivatives with N-containing functional groups

open access: yesBeilstein Journal of Organic Chemistry, 2015
The two isomeric bis(isocyanates) 4,12- and 4,16-di-isocyanato[2.2]paracyclophane, 16 and 28, have been prepared from their corresponding diacids by simple routes.
Henning Hopf   +2 more
doaj   +1 more source

Stimuli‐Responsive Afterglow from Luminescent Liquid Crystal Elastomers

open access: yesAdvanced Materials, EarlyView.
An active glow luminescent system for encoding, signaling, and tracking in dark environments has been developed by integrating inorganic ultralong afterglow phosphors with adaptive liquid crystal elastomer actuators. Abstract Stimuli‐responsive luminescent polymeric materials which combine afterglow emission with mechanical flexibility and adaptability
Lansong Yue   +2 more
wiley   +1 more source

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