Results 201 to 210 of about 34,359 (255)
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Ce(OTf)3-Catalyzed Multicomponent Reaction of Alkynyl Carboxylic Acids, tert-Butyl Isocyanide and Azides for the Assembly of Triazole-Oxazole Derivatives.

ACS Combinatorial Science, 2020
Cerium(III) triflate-catalyzed multicomponent reactions between alkynyl carboxylic acids, tert-butyl isocyanide and organic azides have been developed. In the presence of Ce(OTf)3 (10 mol%), the cascade reaction of one molecule of alkynyl carboxylic acid
M. Cao   +5 more
semanticscholar   +1 more source

Recent advances and applications of p-toluenesulfonylmethyl isocyanide (TosMIC).

Organic and biomolecular chemistry, 2019
Since its introduction in 1972, TosMIC (p-toluenesulfonylmethyl isocyanide) has been recognised as an important building block in organic synthesis and a wide range of reaction strategies have been reported.
Arun Divakar Mathiyazhagan, G. Anilkumar
semanticscholar   +1 more source

Homoleptic Isocyanide Metalates

Angewandte Chemie International Edition, 1998
Novelties and surprises in the chemistry of metal isocyanides: The synthesis and structure determination of homoleptic isocyanide metalates [M(CNXyl)m ]- (M=Co, m=4; M=Mn, m=5; Xyl=2,6-Me2 C6 H3 ) indicate that we need to revise our understanding of transition metal-isocyanide interactions.
openaire   +3 more sources

Silver-Assisted Oxidative Isocyanide Insertion of Ethers: A Direct Approach to β-Carbonyl α-Iminonitriles.

Organic Letters, 2019
An efficient silver-assisted oxidative coupling of simple ethers with tert-butyl isocyanide was realized in the presence of DDQ. The direct synthesis of high density functional β-carbonyl α-iminonitriles was achieved in a single step with high yields ...
LeiYang Zhao   +4 more
semanticscholar   +1 more source

Improvement of the Thermal Stability of Self-Assembled Monolayers of Isocyanide Derivatives on Gold

Journal of Physical Chemistry C, 2019
We report that the thermal stability of self-assembled monolayers (SAMs) of two isocyanide derivatives (1-pentyl isocyanide and benzyl isocyanide) on a gold surface was drastically improved by thei...
Azuho Tsunoi   +6 more
semanticscholar   +1 more source

Synthesis of quinazoline-3-oxides via a Pd(ii) catalyzed azide-isocyanide coupling/cyclocondensation reaction.

Organic and biomolecular chemistry, 2019
A novel and efficient protocol concerning palladium catalyzing the three-component reaction of 2-azidobenzaldehyde, isocyanide, and hydroxylamine hydrochloride is developed.
Ramdas S. Pathare   +5 more
semanticscholar   +1 more source

Accessing α-Arylated Nitriles via BF3·OEt2 Catalyzed Cyanation of para-Quinone Methides Using tert-Butyl Isocyanide as a Cyanide Source.

Journal of Organic Chemistry, 2018
BF3·OEt2 catalyzed 1,6-conjugate addition of tert-butyl isocyanide to para-quinone methides and fuchsones for the synthesis of α-diaryl and α-triaryl nitriles has been reported. This protocol allows α-diaryl- and α-triaryl nitriles to be accessed in good
S. R. Shirsath   +3 more
semanticscholar   +1 more source

p-Nitrophenyl isocyanide

Acta Crystallographica Section C Crystal Structure Communications, 2004
Achiral p-nitrophenyl isocyanide, C(7)H(4)N(2)O(2), crystallizes in the orthorhombic chiral space group P2(1)2(1)2(1). Attractive intermolecular interactions between the nitro O atoms and both aromatic H and nitro N atoms of neighbouring molecules are observed.
Matthias, Zeller, Allen D, Hunter
openaire   +2 more sources

Isocyanide-Induced Activation of Copper Sulfate: Direct Access to Functionalized Heteroarene Sulfonic Esters.

Angewandte Chemie, 2017
A novel and direct approach to alkyl/aryl heteroarene sulfonic esters using copper sulfate as the environmentally benign inorganic sulfonation reagent was first realized with the aid of isocyanide.
Xiaohu Hong, Q. Tan, Bingxin Liu, Bin Xu
semanticscholar   +1 more source

Multicomponent Reactions with Isocyanides

Angewandte Chemie, 2000
Multicomponent reactions (MCRs) are fundamentally different from two-component reactions in several aspects. Among the MCRs, those with isocyanides have developed into popular organic-chemical reactions in the pharmaceutical industry for the preparation of compound libraries of low-molecular druglike compounds.
, Dömling, , Ugi
openaire   +2 more sources

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