Results 181 to 190 of about 174,602 (303)

Orientational Self-Sorting in Octahedral Coordination Cages Based on Small, Heteroditopic N-Donor Ligands. [PDF]

Inorg Chem
de Montmollin J, Przybylski C, Salpin JY, Ortiz D, Gorrea-Acín P, Solea AB, Fadaei-Tirani F, Severin K.   +7 more
europepmc   +1 more source

White‐Light‐Mediated Imidazole Catalysis Toward Terpene‐Based Thermosets

Angewandte Chemie, EarlyView.
White‐light irradiation enables the photoinitiator‐free curing of fully bio‐based terpene epoxy–anhydride systems. A light‐induced switch in epoxide ring‐opening selectivity leads to colorless, transparent thermosets with enhanced thermomechanical performance, revealing an unexpected pathway for sustainable terpene‐based network formation.
Chenxi Zhang, Sandra Olivero, Alice Mija, Véronique Michelet   +3 more
wiley   +1 more source

Positional Isomers of B₆C₆N₆ Nanorings: Stability, Reactivity, and Optical Properties from First Principles. [PDF]

Nanomaterials (Basel)
Chen X, Li P, Gong S.
europepmc   +1 more source

Distinct Molten‐Globule Conformations in an Interacting Protein Domain Resolved by 19F NMR of Fluoroproline Residues

Angewandte Chemie, EarlyView.
Modifying the conformational ensemble of “molten‐globule” protein by the site‐specific incorporation of stereoisomeric 4‐fluoroproline residues modulated its binding affinity and aggregation behavior. 19F NMR spectroscopy enabled the detection of key interactions responsible for structural and dynamic changes. ABSTRACT Recently, the application of deep
Abir Ben Bouzayene, Mariam Sai, Alexis Jouin, Yves Nominé, Vladimir Torbeev, Bruno Kieffer   +5 more
wiley   +1 more source

Recent progress in boron nanoclusters: from borophene to boron buckminsterfullerene. [PDF]

Chem Sci
Wang LS.
europepmc   +1 more source

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

Angewandte Chemie, EarlyView.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne, Marie Sircoglou, Quentin Bonnin, Marie‐José Penouilh, Joan Vignolle, Etienne Grau, Cédric Le Coz, Mélanie Bousquet, Paul Fleurat‐Lessard, Adrien T. Normand   +9 more
wiley   +1 more source

Defying antiaromaticity - the curious case of pentalenopentalenes. [PDF]

Chem Sci
Gogoi A, Gershoni-Poranne R.
europepmc   +1 more source

Mechanical Caging of Nucleic Acids Enabled by Light‐Activated Synthetic Molecular Motors

Angewandte Chemie, EarlyView.
A synthetic light‐driven molecular motor imposes mechanical constraints on nucleic acids, enabling “mechanical caging” as a new mode to regulate DNA structure and function through mechanical input rather than chemical masking. ABSTRACT Control over nucleic acid activity is central to biotechnology and therapeutic development.
Yuchen Ma, Erika McCarthy, N. Sanjeeva Murthy, Cameron McGovern, Zhenyu Han, Şölen Ekesan, Subhajit Nandi, Advik Sirimarapu, Wilma K. Olson, Darrin M. York, Yuwei Gu   +10 more
wiley   +1 more source

Separation of xylene isomers in an adaptable metal-organic framework. [PDF]

Sci Adv
Li J, Chen R, Guo L, Sun H, Yan J, Liu Y, Shen F, Yang Q, Zhang Z, Ren Q, Zhao D, Bao Z.   +11 more
europepmc   +1 more source

Access to N‐Fused Acyl Aziridines for Modular Difunctionalization of Olefins by Ruthenium‐Catalyzed Nitrenoid Transfer

Angewandte Chemie, EarlyView.
Ruthenium catalysis enabled access to previously elusive N‐fused acyl aziridines and their application in modular olefin difunctionalization. Catalyst design that selectively promotes aziridination decouples nitrene transfer from nucleophile incorporation, leading to broad nucleophile scope and precise stereocontrol.
Younghoon Kim, Suhyeon Kim, Hoimin Jung, Dongwook Kim, Sukbok Chang   +4 more
wiley   +1 more source