Results 1 to 10 of about 800,251 (299)

Reactivity of cyclohex-1-enylcarboxylic and 2-methylcyclohex-1-enylcarboxylic acids with diazodiphenylmethane in aprotic solvents [PDF]

open access: yesJournal of the Serbian Chemical Society, 2000
Rate constants for the reaction of diazodiphenylmethane with cyclohex-1-enylcarboxylic acid and 2-methylcyclohex-1-enylcarboxylic acid were determined in nine aprotic solvents, as well as in seven protic solvents, at 30°C using the appropriate ...
Nikolić Jasmina B.   +2 more
doaj   +3 more sources

The kinetics of the reactions of 2-substituted nicotinic acids with diazodiphenylmethane in various alcohols [PDF]

open access: yesJournal of the Serbian Chemical Society, 2003
The rate constants of 2-substituted nicotinic acids in reaction with diazodiphenylmethane (DDM) in eight alcohols at 30ºC have been determined. In order to explain the obtained results through solvent effects, the second order reaction rate constants (k)
MILICA M. MISIC-VUKOVIC   +3 more
doaj   +3 more sources

The influence of the solvent on organic reactivity. Part II. Hydroxylic solvent effects on the reaction rates of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic and 2-(2-substituted [PDF]

open access: yesJournal of the Serbian Chemical Society, 2004
The rate constants for the reaction of diazodiphenylmethane with 2-(2-substituted cyclohex-1-enyl)acetic acids and 2-(2-substituted phenyl)acetic acids, previously determined in seven hydroxylic solvents, were correlated using the total solvatochromic ...
Nikolić Jasmina B.   +2 more
doaj   +1 more source

The reactivity of α,β-unsaturated carboxylic acids. Part XVI. The kinetics of the reaction of cycloalkenecarboxylic and cycloalkenylacetic acids with diazodiphenylmethane in various alcohols [PDF]

open access: yesJournal of the Serbian Chemical Society, 2002
The rate constants for the reaction of diazodiphenylmethane with 1-cyclopentenecarboxylic, 1-cycloheptenecarboxylic, cyclopent-1-enylacetic and cyclohept-1-enylacetic acids were determined in eight alcohols at 30 ºC using the appropriate UV-spectroscopic
Ušćumlić Gordana S.   +2 more
doaj   +1 more source

Ultrasonic on-line spectrophotometric system for reaction kinetic measurements; pp. 52–57 [PDF]

open access: yesProceedings of the Estonian Academy of Sciences, 2012
A unique ultrasonic online spectrophotometric system for kinetic measurements of homogeneous polar reactions under ultrasound was developed. The setup consists of an ultrasonic bath, an HPLC UV/Vis detector, an HPLC pump, a refrigerated heating ...
Sander Piiskop   +2 more
doaj   +1 more source

Investigation of Liberation Mechanism of Electronic Scrap by Impact Energy Measurements and DEM Simulations

open access: yesJournal of MMIJ, 2023
To clarify the mechanism of liberation in the comminution process of electronic scrap (e-scrap), we attempted to express the degree of liberation by first-order kinetic equation related to impact energy.
Takuya TATSUMOTO   +5 more
doaj   +1 more source

Measurement of Eosinophil Kinetics In Vivo

open access: yes, 2021
Radiolabeled leukocyte scans are used in nuclear medicine to detect sites of infection and inflammation. We have previously demonstrated the use of clinical grade immunomagnetic beads to isolate autologous eosinophils and image their distribution in healthy volunteers.
Farahi, Neda   +5 more
openaire   +4 more sources

The impact of tibial torsion measurements on gait analysis kinematics [PDF]

open access: yesActa Ortopédica Brasileira, 2014
Objective: To measure and compare tibial torsion values as assessed by goniometry and three-dimensional kinematics. In addition, the impact of each one of these measurements on kinematic and kinetic results for normal gait was determined.Methods: Twenty ...
Paulo Roberto Garcia Lucareli   +5 more
doaj   +1 more source

Experimental Analyses Emphasize the Stability of the Meisenheimer Complex in a SNAr Reaction Toward Trends in Reaction Pathways

open access: yesFrontiers in Chemistry, 2020
The mechanism of SNAr reactions between 2-chloro-5-nitropyrimidine with primary and secondary alicyclic amines, respectively, have been studied by kinetic measurements.
Paola R. Campodónico   +2 more
doaj   +1 more source

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