Results 91 to 100 of about 87,265 (295)

Triboluminescence of Centrosymmetric Lanthanide β-Diketonate Complexes with Aggregation-Induced Emission

open access: yesMolecules, 2019
Triboluminescence (TL) is a form of light emission induced upon mechanical forces on the material. However, our understanding of this phenomenon is still unclear and more examples are therefore needed in order to elucidate its mechanism.
Ho-Yin Wong   +2 more
doaj   +1 more source

Detection of bacterial spores with lanthanide-macrocycle binary complexes [PDF]

open access: yes, 2009
The detection of bacterial spores via dipicolinate-triggered lanthanide luminescence has been improved in terms of detection limit, stability, and susceptibility to interferents by use of lanthanide−macrocycle binary complexes.
Cable, Morgan L.   +5 more
core   +1 more source

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Lanthanide Chlorides Decrease the Antioxidant Property of Human Serum Albumin

open access: yesOrbital: The Electronic Journal of Chemistry, 2017
Substantial conformational changes of human serum albumin, HSA, induced by Lanthanide chlorides (Ce3+, La3+, Er3+) in phosphate buffer, 10 mmol L-1 at pH 7.4, was studied by Isothermal Titration Calorimetry, ITC.
Mahmood Payeghadr   +2 more
doaj  

Insights into coordination and ligand trends of lanthanide complexes from the Cambridge Structural Database

open access: yesScientific Reports
Understanding lanthanide coordination chemistry can help develop new ligands for more efficient separation of lanthanides for critical materials needs.
Shicheng Li   +2 more
doaj   +1 more source

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

LEAD: Literature Enhanced Ab Initio Discovery of Nitride Dusting Layers for Enhanced Tunnel Magnetoresistance and Lower Resistance Magnetic Tunnel Junctions

open access: yesAdvanced Materials, EarlyView.
Magnetic tunnel junctions (MTJs) using MgO tunnel barriers face challenges of high resistance‐area product and low tunnel magnetoresistance (TMR). To discover alternative materials, Literature Enhanced Ab initio Discovery (LEAD) is developed. The LEAD‐predicted materials are theoretically evaluated, showing that MTJs with dusting of ScN or TiN on ...
Sabiq Islam   +6 more
wiley   +1 more source

Investigating the Structural Factors Influencing the Magnetic Interaction between Individual Copper Spins in the CuCu4 Metallacrown Complex, from Its Bulk Form to Its Adsorption on Au(111)

open access: yesAdvanced Materials Interfaces, EarlyView.
The Cu(II)[12‐MCCu(II)N(Shi)‐4] metallacrown complex (CuCu4) is studied to examine how geometric transformations affect magnetic coupling between copper spins by using ultraviolet photoemission spectroscopy and DFT calculations for the bulk phase and CuCu4 adsorbed on Au(111). While adsorption minimally affects tDOS, exchange coupling constants between
Ariyan Tavakoli   +11 more
wiley   +1 more source

Transparent, Sprayable Plastic Films for Luminescent Down‐Shifted‐Assisted Plant Growth

open access: yesAdvanced Materials Technologies, Volume 10, Issue 6, March 18, 2025.
Spreading the light: A modular approach to down‐shifting europium‐containing polyoxotitanium luminescent cages is developed, allowing their incorporation into sprayable plastic coatings on agricultural greenhouses for accelerated plant growth. Abstract The world's steadily growing population and global heating due to climate change are a threat to food
Rosa Müller   +17 more
wiley   +1 more source

Synthesis, Structure, and Properties of 2D Lanthanide(III) Coordination Polymers Constructed from Cyclotriphosphazene-Functionlized Hexacarboxylate Ligand

open access: yesMolecules
The design and synthesis of novel lanthanide-based coordination polymers (Ln-CPs) from flexible organic ligands is still attractive and challenging. In this work, two isostructural Ln-CPs with a unique 2D network, namely, [Ln2(H3L)2(DMF)]]n (Ln = Dy for ...
Qi Jia   +6 more
doaj   +1 more source

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