Lanthanides in Methylotrophy [PDF]
Lanthanides were previously thought to be biologically inert owing to their low solubility; however, they have recently been shown to strongly impact the metabolism of methylotrophic bacteria. Leading efforts in this emergent field have demonstrated far-reaching impacts of lanthanide metabolism in biology; from the identification of novel roles of ...
Skovran, Elizabeth +2 more
openaire +2 more sources
A Periplasmic Lanthanide Mediator, Lanmodulin, in Methylobacterium aquaticum Strain 22A
Methylobacterium and Methylorubrum species oxidize methanol via pyrroloquinoline quinone-methanol dehydrogenases (MDHs). MDHs can be classified into two major groups, Ca2+-dependent MDH (MxaF) and lanthanide (Ln3+)-dependent MDH (XoxF), whose expression ...
Yoshiko Fujitani +2 more
doaj +1 more source
Enthalpies of formation of lanthanide oxyapatite phases [PDF]
A family of lanthanide silicates adopts an oxyapatite-like structure with structural formula Ln9.33∎0.67(SiO4)6O2 (Ln 4 La, Sm, Nd, Gd, ∎ = vacancy).
Helean, K. B. +4 more
core +1 more source
Bis(η5-cyclopentadienyl)(2-{[(2-methoxyphenyl)imino]methyl}phenolato-κ3O,N,O′)terbium
The air- and moisture-sensitive title compound, [Tb(C5H5)2(C14H12NO2)], was synthesized from tris(cyclopentadienyl)(tetrahydrofuran)terbium and 2-{[(2-methoxyphenyl)imino]methyl}phenol. Each Tb atom is coordinated by two cyclopentadienyl ligands in an η5-
Mikhail E. Minyaev +3 more
doaj +1 more source
Ultrabright Lanthanide Nanoparticles [PDF]
AbstractInvited for this month's cover are the collaborating groups of Dr. Loïc J. Charbonnière at CNRS/Université de Strasbourg, France and Dr. Ka‐Leung Wong at Hong Kong Baptist University, Hong Kong. The cover picture shows terbium‐doped LaF3 nanoparticles that are surface functionalized by photon‐harvesting antenna ligands.
Goetz, Joan +9 more
openaire +5 more sources
Extraction of crystal-field parameters for lanthanide ions from quantum-chemical calculations
A simple method for constructing effective Hamiltonians for the 4fN and 4fN-15d energy levels of lanthanide ions in crystals from quantum-chemical calculations is presented.
Duan, C. K. +4 more
core +1 more source
Application of Chiral Lanthanide-induced Shift Reagents to Optically Active Cations: the Use of Tris[3-(trifluoromethylhydroxymethylene)-( + )-camphorato]europium(III) to Determine the Enantiomeric Purity of Tris(phenanthroline)ruthenium(II) Dichloride [PDF]
In non-polar solvents, chiral europium complexes provide attractive n. m. r. shift reagents to resolve spectra of optically active cations, and, in particular, for tris(phenanthroline)ruthenium dichloride,^1H n. m. r. shift differences of up to 0.7 p.p.m.
Barton, Jacqueline K., Nowick, James S.
core +1 more source
Despite the fact that in the mass consciousness nuclear power is associated with increased environmental risks, this type of energy today remains one of the cleanest, most efficient and carbon neutral. Further development of nuclear energy is hampered by
Mikhail Alyapyshev +2 more
doaj +1 more source
Self-induced spin glass state in elemental and crystalline neodymium
Spin glasses are a highly complex magnetic state of matter, intricately linked to spin frustration and structural disorder. They exhibit no long-range order and exude aging phenomena, distinguishing them from quantum spin liquids. We report a new type of
Bergman, Anders +10 more
core +1 more source
New Composite Contrast Agents Based on Ln and Graphene Matrix for Multi-Energy Computed Tomography
The subject of the current research study is aimed at the development of novel types of contrast agents (CAs) for multi-energy computed tomography (CT) based on Ln–graphene composites, which include Ln (Ln = La, Nd, and Gd) nanoparticles with a size of 2–
Evgeniya V. Suslova +8 more
doaj +1 more source

