Connectivity-Rewired Construction of Hydrogen-Bonded Azo-Macrocycles Enables Photoswitchable Recognition of Lithium Ions. [PDF]
Tan C +7 more
europepmc +1 more source
During coffee bean and cherry washing, contaminants are released into water, making this process a major source of water pollution. Chlorogenic acid can be efficiently detected using hybrid zeolite–porphyrin materials by measuring fluorescence quenching, achieving detection limits lower than current regulatory thresholds.
João Otávio Donizette Malafatti +10 more
wiley +1 more source
Massive barcode-free chemical screenings enable the discovery of bioactive macrocycles with passive membrane permeability. [PDF]
Mata JM +10 more
europepmc +1 more source
Metal‐Free Ligand‐Centered Radical Scavenging in Pyridine‐Modified Tetraaza Macrocycles
Ligand‐centered hydrogen‐atom transfer in pyridinophane macrocycles generates delocalized radicals, with Py2N2 enabling cooperative captodative stabilization and enhanced DPPH• quenching. Pyridine‐modified tetraaza macrocycles are widely studied as ligand platforms for metal coordination, yet their intrinsic redox and radical reactivity in the absence ...
Christina Mantsorov +9 more
wiley +1 more source
Covalent-Bond-Directed Synthesis of Rotaxanes from Macrocyclic Diaryliodonium Salts. [PDF]
Hamamura K +6 more
europepmc +1 more source
Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley +1 more source
Orthogonal cation and anion template-directed synthesis of a heteroditopic [3]catenane for ion-pair recognition. [PDF]
Tay HM +3 more
europepmc +1 more source
Infrared Irradiation‐Assisted Pd/Cu Catalysis for Sustainable C–N Cross‐Coupling Reactions
A combined Pd/Cu catalytic system is demonstrated to be highly effective in promoting infrared irradiation‐assisted Buchwald–Hartwig aminations under nonanhydrous and open‐air conditions, using only a stoichiometric amount of a green reaction solvent.
Ambra M. Fiore +4 more
wiley +1 more source
A Longitudinal Evaluation of Bone Mineral Density Across a Macrocycle in Highly Trained Female Athletes: A Systematic Review. [PDF]
Black GM, Wells M, Devlin BL.
europepmc +1 more source
Diarylethene‐containing cyclic tubulysin analogues were designed, synthesized, and evaluated as light‐responsive cytotoxic agents. One analogue showed reversible photoswitching, photoregulated tubulin polymerization inhibition, and photoform‐dependent cytotoxicity.
Anna Iampolska +9 more
wiley +1 more source

